Generation of tunable narrow-band terahertz (THz) radiation perpendicular to the surface of periodically poled lithium niobate by optical rectification of femtosecond pulses is reported. The generated THz radiation can be tuned by use of different poling periods and different observation angles, limited only by the available bandwidth of the pump pulse. Typical bandwidths were 50-100 GHz, depending on the collection angle and the number of periods involved.
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Angew Chem Int Ed Engl
January 2025
Colorado State University, Chemistry and Biochemistry, 301 W. Pitkin Street, 215 UCB, 80523, United States, 80523, Fort Collins, UNITED STATES OF AMERICA.
Synthetic polymers have found widespread use with functional lifetimes from seconds to decades. However, the lack of end-of-life treatment for these plastics is causing a significant environmental and human health crisis due to their persistence and bioaccumulation. Upcycling post-consumer plastic waste to products with inherent recyclability is an attractive strategy to tackle this problem, as it can broaden the range of accessible materials and uncover unprecedented features while dealing with current plastic waste.
View Article and Find Full Text PDFTalanta
January 2025
Department of Chemistry, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia.
Annealing plays a crucial role for in enhancing the gas sensing properties of MOF-derived TiO (MIL-125). Generally, TiO transforms into different polymorphs (anatase, rutile, and brookite) during annealing, each with unique crystal structures and gas sensing properties. The aim of this research was to investigate the impact of annealing (500-650 °C) on the properties of MIL-125, which had not been previously studied.
View Article and Find Full Text PDFLangmuir
January 2025
Gordon Center for Medical Imaging, Department of Radiology, Massachusetts General Hospital and Harvard Medical School, Boston, Massachusetts 02114, United States.
Nanocarriers have shown significant promise in the diagnosis and treatment of various diseases, utilizing a wide range of biocompatible materials such as metals, inorganic substances, and organic components. Despite diverse design strategies, key physicochemical properties, including hydrodynamic diameter, shape, surface charge, and hydrophilicity/lipophilicity, are crucial for optimizing biodistribution, pharmacokinetics, and therapeutic efficacy. However, these properties are often influenced by drug payload, presenting an ongoing challenge in developing versatile platform technologies for theranostics.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, Singapore 117585, Singapore.
Nanomaterials that engage in well-defined and tunable interactions with proteins are pivotal for the development of advanced applications. Achieving a precise molecular-level understanding of nano-bio interactions is essential for establishing these interactions. However, such an understanding remains challenging and elusive.
View Article and Find Full Text PDFACS Catal
October 2024
Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, Florida 32611, United States.
A class of generated Lewis acid (LA) activated acridine complexes is reported, which act as potent photochemical catalysts for the oxidation of a variety of protected secondary amines. Acridine/LA complexes exhibit tunable excited state reduction potentials ranging from +2.07 to 2.
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