Single Scan 2D NMR Spectroscopy on a 25 T Bitter Magnet.

Chem Phys Lett

Department of Chemical Physics, Weizmann Institute of Science, 76100 Rehovot, Israel.

Published: July 2007

2D NMR relies on monitoring systematic changes in the phases incurred by spin coherences as a function of an encoding time t(1), whose value changes over the course of independent experiments. The intrinsic multiscan nature of such protocols implies that resistive and/or hybrid magnets, capable of delivering the highest magnetic field strengths but possessing poor temporal stabilities, become unsuitable for 2D NMR acquisitions. It is here shown with a series of homo- and hetero-nuclear examples that such limitations can be bypassed using recently proposed 2D "ultrafast" acquisition schemes, which correlate interactions along all spectral dimensions within a single scan.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2084366PMC
http://dx.doi.org/10.1016/j.cplett.2007.06.016DOI Listing

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