The synthesis of microporous materials has been an important element of solid state chemistry over the past years and remains so today. The emergence of possible new applications has driven interest towards synthesis of new materials. This article reviews the application of macrocycles as structure-directing agents (SDAs) in the pursuit of these important new materials.
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http://dx.doi.org/10.1039/b710352b | DOI Listing |
J Colloid Interface Sci
January 2025
Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province, School of Resources and Materials, Northeastern University at Qinhuangdao, Qinhuangdao 066004, PR China. Electronic address:
Chem Commun (Camb)
January 2025
Institute of Crystalline Materials, Shanxi University, Taiyuan 030006, Shanxi, China.
This study introduces the first metal organic framework using ammelide as the organic ligand, showcasing stability in boiling water and high sensitivity in detecting dichromate ions.
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January 2025
Laboratorio de Fisicoquímica y Reactividad de Superficies (LaFReS), Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México Circuito Exterior s/n, CU, Coyoacán 04510 Ciudad de México Mexico
Hybrid organic-inorganic perovskites (HOIPs) are widely studied for their potential in optoelectronic devices due to their unique semiconductor features. Porous HOIPs are extremely rare, with (APOSS)[CuCl] being one of the very few examples, featuring 12 Å pores within its lattice. Reed and coworkers (C.
View Article and Find Full Text PDFMolecules
December 2024
School of Food and Pharmaceutical Engineering, Zhaoqing University, Zhaoqing 526061, China.
The development of lanthanide-organic frameworks (Ln-MOFs) using for luminescence sensing and selective gas adsorption applications is of great significance from an energy and environmental perspective. This study reports the solvothermal synthesis of a fluorine-functionalized 3D microporous Tb-MOF with a face-centered cubic () topology constructed from hexanuclear clusters (TbO) bridged by fdpdc ligands, formulated as {[Tb(fdpdc)(-OH)(HO)]·4DMF} (), (fdpdc = 3-fluorobiphenyl-4,4'-dicarboxylate). Complex displays a 3D framework with the channel of 7.
View Article and Find Full Text PDFNat Chem
January 2025
Laboratory of Advanced Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM), College of Chemistry and Materials, Fudan University, Shanghai, P. R. China.
The synthesis of mesoporous metal-organic frameworks (meso-MOFs) is desirable as these materials can be used in various applications. However, owing to the imbalance in structural tension at the micro-scale (MOF crystallization) and the meso-scales (assembly of micelles with MOF subunits), the formation of single-crystal meso-MOFs is challenging. Here we report the preparation of uniform single-crystal meso-MOF nanoparticles with ordered mesopore channels in microporous frameworks with definite arrangements, through a cooperative assembly method co-mediated by strong and weak acids.
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