Trialkylsiloxy-modified Ta(v) centers on mesoporous silica exhibit excellent selectivity for epoxide formation (>98% after 2 h) in the oxidation of cyclohexene using aqueous H2O2 as the oxidant; the modified catalysts exhibit an increased lifetime, retaining high selectivity after 6 h of reaction (>95% epoxide).
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| http://dx.doi.org/10.1039/b706443h | DOI Listing |
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