Toxic silo gases are a potential danger to livestock housed in close proximity to roughage silos. These gases, such as nitrogen dioxide (NO2), may be produced during the early stages of (maize and grass) silage making. In humans, inhalation of these gases causes a condition known as 'Silo Filler's Disease' (SFD), which is a recognized occupational hazard for workers in upright forage silos in many countries. NO2 accumulates on top of silage, is inhaled by workers, and reacts with water on the airway surfaces to form nitrous acid, which damages the lung and causes pulmonary oedema, bronchiolitis, and death in severe cases. On a dairy farm, a cloud of reddish-brown NO2 gas (which is heavier than air) was noticed to escape from underneath the plastic sheet of a horizontal maize bunker and to enter a cubicle house for dairy cows 1 day after ensiling. Eleven cows became dyspnoeic, 3 of which subsequently died. A combination of weather conditions, an insufficient sand load on the maize bunker, the utilization of a lactobacillus starter culture, and the close proximity of the silo to the cubicle house may have caused the incident.
Download full-text PDF |
Source |
---|
Environ Int
January 2025
School of Geospatial Engineering and Science, Sun Yat-sen University, Zhuhai 519082, China. Electronic address:
Ozone (O) is a significant contributor to air pollution and the main constituent ofphotochemical smog that plagues China. Nitrogen dioxide (NO) is a significant air pollutant and a critical trace gas in the Earth's atmosphere. The presence of O and NO has detrimental effects on human health, the ecosystem, and agricultural production.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Physical Chemistry, Gdańsk University of Technology, Narutowicza 11/12, Gdańsk, 80-233, Poland.
The study investigated the degradation of 3-methoxy-1-propanol (3M1P) by OH using the M06-2X/6-311++G(d, p) level, with CCSD(T) single-point corrections. We focused on hydrogen atom abstraction from various alkyl groups within the molecule. The rate coefficient for 3M1P degradation was calculated from the sum of the rate coefficients corresponding to the removal of H-atoms from primary (-CH), secondary (-CH-), tertiary (-CH< ), and alcohol (-ΟH) groups.
View Article and Find Full Text PDFEnviron Res
January 2025
Xi'an Key Laboratory of Advanced Photo-Electronics Materials and Energy Conversion Device, Technological Institute of Materials & Energy Science (TIMES), Xijing University, Xi'an 710123, PR China; School of Artificial Intelligence, Optics and Electronics (iOPEN), Northwestern Polytechnical University, Xi'an 710072, Shaanxi, PR China. Electronic address:
This paper focuses on the research background of zeolite-based photocatalytic materials, the role of zeolites in photocatalytic materials, and their application in various fields. It focuses on the critical roles of zeolites in photocatalytic materials and their application prospects. It outlines the mechanisms of zeolites in different photocatalytic materials, including adsorption, structural stabilization, domain-limiting, electric field, catalysis, ion exchange, shape-selective, and solvation, which elucidates the potential advantages of zeolites in photocatalytic materials.
View Article and Find Full Text PDFInt J Epidemiol
December 2024
School of Nutrition and Public Health, College of Health, Oregon State University, Corvallis, OR, USA.
Background: Billions of dollars have been spent implementing regulations to reduce traffic-related air pollution (TRAP) from exhaust pipe emissions. However, few health studies have evaluated the change in TRAP emissions and associations with infant health outcomes. We hypothesize that the magnitude of association between vehicle exposure measures and adverse birth outcomes has decreased over time, parallelling regulatory improvements in exhaust pipe emissions.
View Article and Find Full Text PDFJ Mol Model
January 2025
Department of Chemistry, Military Institute of Engineering, Praça General Tibúrcio 80, Rio de Janeiro, Brazil.
Context: Nitrocellulose, widely used in energetic materials, is prone to thermal and chemical degradation, compromising safety and performance. Stabilizers are molecules used in the composition of nitrocellulose-based propellants to inhibit the autocatalytic degradation process that produces nitrous gases and free nitric acids. Curcumin, (1E,6E)-1,7-bis(4-hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione, known for its antioxidant properties and a potential green stabilizer, was investigated using Density Functional Theory (DFT) focusing on its interaction with nitrogen dioxide.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!