A versatile electronic hole in one-electron oxidized NiIIbis-salicylidene phenylenediamine complexes.

Chem Commun (Camb)

Département de Chimie Moléculaire - Chimie Inorganique Redox Biomimétique (CIRE) - UMR CNRS 5250, Université J. Fourier, B. P. 53, 38041 Grenoble cedex 9, France.

Published: November 2007

The nickel complexes 1(+)-3(+) exhibit a delocalized radical character, the extent of which depends on the electronic properties of the phenolate para-substituent.

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Source
http://dx.doi.org/10.1039/b710027bDOI Listing

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