We have investigated the fission following a Coulomb explosion in argon clusters (up to Ar800) irradiated by a femtosecond infrared laser with moderate intensity IL approximately 10(13) W cm(-2). We report the a priori surprising observation of well-defined velocity distributions of the ionized fragments Ar+n<50. This is interpreted by the formation of a valence shell excited charged ion, followed by relaxation, charge transfer by autoionizing collision at very short distance, and asymmetric fission.
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http://dx.doi.org/10.1103/PhysRevLett.99.103401 | DOI Listing |
Nanomaterials (Basel)
December 2024
Department of General Physics, Kazan National Research Technical University Named After A.N. Tupolev-KAI, Kazan 420111, Russia.
In this work, within the framework of a self-consistent model of arc discharge, a simulation of plasma parameters in a mixture of argon and methane was carried out, taking into account the evaporation of the electrode material in the case of a refractory and non-refractory cathode. It is shown that in the case of a refractory tungsten cathode, almost the same methane conversion rate is observed, leading to similar values in the density of the main methane conversion products (C, C, H) at different values of the discharge current density. However, with an increase in the current density, the evaporation rate of copper atoms from the anode increases, and a jump in the - characteristic is observed, caused by a change in the plasma-forming ion.
View Article and Find Full Text PDFMolecules
December 2024
Institute of Ion Physics and Applied Physics, University of Innsbruck, Technikerstraße 25, 6020 Innsbruck, Austria.
Machine learning potential energy functions can drive the atomistic dynamics of molecules, clusters, and condensed phases. They are amongst the first examples that showed how quantum mechanics together with machine learning can predict chemical reactions as well as material properties and even lead to new materials. In this work, we study the behaviour of tungsten trioxide (WO) surfaces upon particle impact by employing potential energy surfaces represented by neural networks.
View Article and Find Full Text PDFJ Phys Chem A
December 2024
Department of Chemistry, University of Missouri, Columbia, Missouri 65211, United States.
State-to-state spin-orbit changing collisions of vibrationally excited nitric oxide (NO) with argon (Ar) were studied across a wide collision energy range from 3.5 to 11,200 cm (0.43 meV to 1.
View Article and Find Full Text PDFUltrason Sonochem
December 2024
Third Institute of Physics, Georg-August-University Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen, Germany. Electronic address:
Light emissions from cavitating liquids serve as a diagnostic tool for chemical activity, bubble collapse conditions, or excited species. Here we demonstrate the influence of mechanical stirring on sonoluminescence (SL) and sonochemiluminescence (SCL) emissions emerging in the presence of dissolved sodium salts and luminol in different sonicated liquids. In the systems investigated, driven in the 20-40 kHz range, stirring can change the spatial distribution of blue/white broadband SL emissions and of the orange sodium D-line emission, as well as their relative intensities.
View Article and Find Full Text PDFSci Rep
November 2024
Faculty of Energy and Fuels, AGH University of Krakow, al. Adama Mickiewicza 30, Krakow, 30-059, Poland.
This article presents the unique research results of the comprehensive analysis of the porous structure of activated carbons obtained from biomass waste materials from the wood industry during activation in an air atmosphere. The porous structure was analysed on the basis of nitrogen and argon adsorption isotherms via complementary multi-method analysis, i.e.
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