The structures of orthorhombic bis[pentaammineaquacobalt(III)] tetra-mu(2)-fluorido-tetradecafluoridotrizirconium(IV) hexahydrate (space group Ibam), [Co(NH(3))(5)(H(2)O)](2)[Zr(3)F(18)].6H(2)O, (I), and bis[hexaamminecobalt(III)] tetra-mu(2)-fluorido-tetradecafluoridotrizirconium(IV) hexahydrate (space group Pnna), [Co(NH(3))(6)](2)[Zr(3)F(18)].6H(2)O, (II), consist of complex [Co(NH(3))(x)(H(2)O)(y)](3+) cations with either m [in (I)] or overline{1} and 2 [in (II)] symmetry, [Zr(3)F(18)](6-) anionic chains located on sites with 222 [in (I)] or 2 [in (II)] symmetry, and water molecules.

Download full-text PDF

Source
http://dx.doi.org/10.1107/S010827010704108XDOI Listing

Publication Analysis

Top Keywords

tetra-mu2-fluorido-tetradecafluoridotrizirconiumiv hexahydrate
8
hexahydrate space
8
space group
8
[in ii]
8
ii] symmetry
8
double complexes
4
complexes [conh35h2o]2[zr3f18]6h2o
4
[conh35h2o]2[zr3f18]6h2o [conh36]2[zr3f18]6h2o
4
[conh36]2[zr3f18]6h2o structures
4
structures orthorhombic
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!