Microwave irradiation of alkenone O-phenyl oximes produces iminyl radicals that ring close to yield dihydropyrrole derivatives; pyrroles and pyridines can be obtained from related precursors.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/b712582h | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Microwave-assisted syntheses of N-heterocycles using alkenone-, alkynone- and aryl-carbonyl O-phenyl oximes: formal synthesis of neocryptolepine.
J Org Chem
July 2008
School of Chemistry, EaStChem, University of St. Andrews, St. Andrews, Fife KY16 9ST, UK.
This research aimed to provide a new and "clean" synthetic method that would enable both known and novel N-heterocycles to be prepared efficiently. O-Phenyl oximes were found to be excellent precursors for iminyl radicals with a variety of acceptor side chains. Dihyropyrroles were made in good yields from O-phenyl oximes containing pent-4-ene acceptors.
View Article and Find Full Text PDFMicrowave-assisted preparations of dihydropyrroles from alkenone O-phenyl oximes.
Chem Commun (Camb)
October 2007
University of St. Andrews, School of Chemistry, EaStChem, St. Andrews, Fife, UK KY16 9ST.
Microwave irradiation of alkenone O-phenyl oximes produces iminyl radicals that ring close to yield dihydropyrrole derivatives; pyrroles and pyridines can be obtained from related precursors.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!