Current mathematical scintillation theory describing laser propagation through the atmosphere has been developed for terrestrial environments. Scintillation expressions valid in all regimes of optical turbulence for propagation in the maritime environment, based on what we believe to be a newly developed marine atmospheric spectrum, have been developed for spherical waves. Path average values of the structure parameter, C(n)(2), were inferred from optical scintillation measurements of a diverged laser beam propagating in a marine environment, using scintillation expressions based on both terrestrial and marine refractive index spectra. In the moderate-to-strong fluctuation regime, the inferred marine C(n)(2) values were about 20% smaller than inferred terrestrial C(n)(2) values, but a minimal difference was observed in the weak fluctuation regime. Measurements of angle-of-arrival fluctuations were used to infer C(n)(2) values in the moderate-to-strong fluctuation regime, resulting in values of the structure parameter that were at least an order of magnitude larger than the two scintillation-inferred C(n)(2) values.
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http://dx.doi.org/10.1364/josaa.24.003198 | DOI Listing |
Molecules
January 2025
Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060, Nishikawatsu, Matsue 690-8504, Shimane, Japan.
A series of luminescent bis-cyclometalated iridium complexes with 2,2':6',2″-terpyridine (tpy), [Ir()(tpy)]PF ( = 2-phenylpyridinate (ppy) for ; benzo[h]quinolinate (bzq) for ; 1-phenylisoquinolinate (piq) for ; and 2-phenylbenzothiazolate (pbt) for ), have been synthesized and structurally characterized. Single-crystal X-ray diffraction analyses reveal that the tpy ligands of - are coordinated to the iridium center in a bidentate fashion, and the uncoordinated pendant pyridine rings in the tpy ligands of - form intramolecular π-π stacking interactions with a phenyl moiety of ligands. In addition, the pendant pyridine ring in the tpy ligand of forms an intramolecular hydrogen bonding interaction, unlike in -.
View Article and Find Full Text PDFZhonghua Wai Ke Za Zhi
January 2025
Department of General Surgery, First Medical Center, Chinese People's Liberation Army General Hospital, Beijing100853, China.
To explore the efficacy and factors affecting the treatment of gastric cancer liver metastasis (GCLM) with immune checkpoint inhibitors (ICI). This is a retrospective cohort study. Clinical and pathological data of 588 patients with GCLM treated at the Department of General Surgery, First Medical Center, People's Liberation Army General Hospital, from January 2018 to December 2022 were retrospectively collected.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt.
Natural polymer-based hydrogels may act as versatile platforms in controlled drug delivery. In this regard, photoactive κ-carrageenan (κ-Crg) hydrogels modified with cinnamate (CN) groups are developed for pH-sensitive release of drugs. κ-Crg-CN derivatives containing 17 %, 33 %, and 49 % cinnamate contents, named κ-Crg-CN1, κ-Crg-CN2, and κ-Crg-CN3, respectively, are prepared and cross-linked by UV-induced [2π + 2π] cycloaddition.
View Article and Find Full Text PDFJ Colloid Interface Sci
March 2025
Liaoning Key Lab of Lignocellulose Chemistry and BioMaterials, Liaoning Collaborative Innovation Center for Lignocellulosic Biorefinery, College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China. Electronic address:
The construction of p-n heterojunction is considered a prominent method for promoting efficient separation/migration of photoinduced carriers, thereby enhancing photocatalytic performance. Herein, a series of nanoflower spherical Co(OH)@CN-x p-n heterojunction photocatalysts were fabricated using a simplified one-step hydrothermal strategy. Notably, Co(OH)@CN-2 exhibited optimal performance, showcasing a carbon monoxide (CO) evolution rate of 46.
View Article and Find Full Text PDFChem Asian J
January 2025
School of Physical Sciences, Jawaharlal Nehru University, New Delhi, 110067, India.
Herein, we have reported a series of cationic aggregation-induced emission (AIE) active iridium(III) complexes (Ir1-Ir5) of the type [Ir(C N)(N N)]Cl, wherein C N is a cyclometalating 2-phenylbenzimidazole ligand with varying alkyl chain lengths and N N is a 2,2'-bipyridine ligand attached to bis-polyethylene glycol chains, for the treatment of bacterial infections. The AIE phenomenon of the complexes leveraged for detecting bacteria by fluorescence microscopy imaging that displayed a strong red emission in Gram-positive bacteria. The antibacterial activity of the complexes assessed against Gram-positive methicillin-sensitive S.
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