A hydrothermal approach employing an amine as reducing agent enables synthesis of an analogue of the arsenato(iii)-oxovanadate {V(15)As(6)}, representing the first systematic variation of this intensely studied magnetic system.
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[V(IV)15Sb(III)6O42]6-: an antimony analogue of the molecular magnet [V15As6O42(H2O)]6-.
Dalton Trans
August 2007
Christian-Albrechts-Universität zu Kiel, Institut für Anorganische Chemie, D-24098, Kiel, Germany.
A hydrothermal approach employing an amine as reducing agent enables synthesis of an analogue of the arsenato(iii)-oxovanadate {V(15)As(6)}, representing the first systematic variation of this intensely studied magnetic system.
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