The behaviour and the effects of xenobiotics including pharmaceuticals and fragrances in the environment are widely unknown. In order to improve our knowledge, field investigations and modelling approaches for the entire area of the city of Halle/Saale, Germany, were performed. The distribution of the concentration values and mass fluxes are exemplified using indicators such as Bisphenol A, t-Nonylphenol, Carbamacepine, Galaxolide, Tonalide, Gadolinium and isotopes. Concentrations at a magnitude of ng/L to microg/L were found ubiquitously in the ground and surface waters. Using the concentration values, the impact of the city concerning the indicators was not always evident. Only the assessment of the mass fluxes shows significant urban impacts along the city passage. The calculation of the mass fluxes shows increasing values for all investigated xenobiotics during the city passage; only Bisphenol A stagnates. A balance model of water and indicator mass fluxes was built up for the entire city area.
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http://dx.doi.org/10.1016/j.envpol.2007.05.033 | DOI Listing |
Metabolomics
January 2025
Laboratory of Applied Mass Spectrometry, Department of Cellular and Molecular Medicine, KU Leuven, Leuven, Belgium.
Introduction: Hemodynamic forces play a crucial role in modulating endothelial cell (EC) behavior, significantly influencing blood vessel responses. While traditional in vitro studies often explore ECs under static conditions, ECs are exposed to various hemodynamic forces in vivo. This study investigates how wall shear stress (WSS) influences EC metabolism, focusing on the interplay between WSS and key metabolic pathways.
View Article and Find Full Text PDFMethodsX
June 2025
Dipartimento di Scienze Agrarie, Forestali e Alimentari, Università di Torino, Largo Paolo Braccini 2, 10095 Grugliasco (TO), Italy.
The most frequently used environmental assessment methods are often applied, through a product-based approach, to analyse a single productive process, but such methods neglect the interactions that characterise complex and integrated biological systems (CIS), and often only consider the negative impacts. In order to overcome these gaps and since a material balance can highlight the relationships and interactions of a CIS, a systemic carbon (C) balance is here proposed as a complementary analysis tool to highlight the relationships that exist between different productive processes carried out by the same production unit and to characterise its environmental role. The method was applied to a beef farm consortium to its validation.
View Article and Find Full Text PDFSci Total Environ
January 2025
Key Laboratory of Coastal Environment and Resources of Zhejiang Province, School of Engineering, Westlake University, Hangzhou 310024, China. Electronic address:
Saltmarshes serve as repositories for various metal species, primarily due to vegetation removal and mineralization processes. However, the significance of potassium (K), one of the three major nutrients (nitrogen, phosphorus, and K) essential for plant growth, has often been overlooked, particularly in the context of saltmarshes where the mechanisms of K transport via porewater exchange remain poorly understood. To address this knowledge gap, we conducted field observations and laboratory analysis, and developed a Rn mass balance model to quantify K fluxes via porewater exchange under physical, biological, and anthropogenic drivers.
View Article and Find Full Text PDFEnviron Sci Process Impacts
January 2025
Eberhard Karls University of Tübingen, Department of Geosciences, Schnarrenbergstraße 94-96, 72076 Tübingen, Germany.
Concentrations of pollutants like pharmaceuticals in soils typically decrease over time, though it often remains unclear whether this dissipation is caused by the transformation of the pollutant or a decreasing extractability. We developed a mathematical model that (1) explores the plausibility of different dissipation pathways, and (2) allows the quantification of concentration differences between aqueous soil extracts and soil solution. The model considers soil particles as uniform spheres, kinetic sorption towards an equilibrium (Freundlich model), and two dissipation pathways, irreversible transformation and mineralization (following 1 order kinetics) as well as the formation of non-extractable residues intraparticle diffusion.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
State Key Laboratory of Water Environment Simulation, School of Environment, Beijing Normal University, Beijing 100875, China.
Atrazine (ATR) is an endocrine disruptor known for its persistence and mobility. While the diffuse characteristics and potential risks of ATR have been extensively studied, its transregional migration and degradation characteristics have received less attention. In this study, a modified mass balance approach considering the diffuse source (DS), tributaries, water resource usage, degradation, adsorption, and evaporation was developed based on the traditional mass balance framework and field sampling to estimate the DS fluxes of ATR in a large river basin.
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