AI Article Synopsis
- A new microporous metal-organic framework (Zn(ADC)(4,4'-Bpe)(0.5).xG) was developed, featuring a complex cubic structure.
- The framework has small pores measuring approximately 3.4 x 3.4 angstroms, which enhances its selective sorption capabilities.
- The activated form of this material shows a strong preference for absorbing hydrogen over nitrogen, hydrogen over carbon monoxide, and carbon dioxide over methane.
Article Abstract
A microporous metal-organic framework Zn(ADC)(4,4'-Bpe)(0.5).xG [1; ADC = 4,4'-azobenzenedicarboxylate, 4,4'-Bpe = trans-bis(4-pyridyl)ethylene, G = guest molecules] with a triply interpenetrative primitive cubic net was synthesized and characterized. With pores of about 3.4 x 3.4 A, the activated 1a exhibits highly selective sorption behavior toward H(2)/N(2), H(2)/CO, and CO(2)/CH(4).
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| http://dx.doi.org/10.1021/ic7014034 | DOI Listing |
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