Titanium-manganese compound with a chiral Mn3Ti center.

Inorg Chem

Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie, Wrocław, Poland.

Published: October 2007

We have shown here for the first time a facile route to the molecular compound [Mn3Ti(mu3-OCH2CH2OCH3)2(mu-OCH2CH2OCH3)3(mu-Cl)Cl2(OiPr)2] with a Mn3Ti motif, where the Ti atom is in the chiral position and the Mn atoms occupy nonchiral sites.

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Source
http://dx.doi.org/10.1021/ic7013094DOI Listing

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We have shown here for the first time a facile route to the molecular compound [Mn3Ti(mu3-OCH2CH2OCH3)2(mu-OCH2CH2OCH3)3(mu-Cl)Cl2(OiPr)2] with a Mn3Ti motif, where the Ti atom is in the chiral position and the Mn atoms occupy nonchiral sites.

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