Studies of germanium and silicon by x-ray diffraction reveal that their crystal structure changes at high pressures from the semiconducting diamond-type structure to the metallic white tin structure, in analogy to the known "gray" to "white" transition in tin itself.
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http://dx.doi.org/10.1126/science.139.3556.762 | DOI Listing |
Inorg Chem
January 2025
State Key Laboratory of Superhard Materials and Key Laboratory of Material Simulation Methods & Software of Ministry of Education, College of Physics, Jilin University, Changchun 130012, China.
Superconducting hydrides exhibiting a high critical temperature () under extreme pressures have garnered significant interest. However, the extremely high pressures required for their stability have limited their practical applications. The current challenge is to identify high- superconducting hydrides that can be stabilized at lower or even ambient pressures.
View Article and Find Full Text PDFSci Rep
January 2025
School of Resources and Civil Engineering, Northeastern University, Shenyang, 110819, China.
Based on the symmetric initiation mechanism of double-wing cracks in coal rock mass induced by high-pressure electro-recoil water pressure, fracturing experiments have been performed on coal rock mass under different water pressures and discharge conditions using high-voltage electric pulse hydraulic fracturing devices. Combined with CT scans, the crack spatial distribution inside the post-break coal rock mass was analyzed and found that the edge of the water injection hole is prone to produce double-wing cracks along the drilling hole diameter. ABAQUS is used to verify the physical test and extend the test conditions, the geometric parameter change, morphological expansion rule and crack initiation mechanism of double-wing crack in coal rock mass under different discharge conditions and ground stress conditions are studied.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Key Laboratory of Pulp and Paper Science and Technology of Shandong Province, Ministry of Education, State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, Shandong, China.
The high salt content and color are regarded as a major challenge to the reuse of industrial wastewater. In the present study, the application of cellulose acetate reverse osmosis (RO) membrane in combination with microfiltration (MF), ultrafiltration (UF), or nanofiltration (NF) process was investigated in the purification of biological and Fenton treated pulp and paper wastewater. In the first step, the effect of pH and inlet pressures on the membrane fouling was investigated.
View Article and Find Full Text PDFJ Environ Manage
January 2025
School of Environment, Tsinghua University, Beijing, 100084, China; Jiangsu Collaborative Innovation Center of Technology and Material of Water Treatment, Suzhou University of Science and Technology, Suzhou, 215009, China. Electronic address:
Urban flooding poses a significant risk to cities worldwide, exacerbated by increasing urbanization and climate change. Effective flood risk management requires comprehensive assessments considering the complex interaction of social, economic, and environmental factors. This study developed an innovative Urban Flood Risk Index (FRI) to quantify and assess flood risk at the sub-catchment level, providing a tool for evidence-based planning and resilient infrastructure development.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Wolfson Department of Chemical Engineering, Technion - Israel Institute of Technology, Haifa 3200003, Israel.
The pressure-dependent reactions on the NH potential energy surface (PES) have been investigated using CCSD(T)-F12/aug-cc-pVTZ-F12//B2PLYP-D3/aug-cc-pVTZ. This study expands the NH PES beyond the previous literature by incorporating a newly identified isomer, NHN, along with additional bimolecular reaction channels associated with this isomer, namely NNH + H and HNN(S) + H. Rate coefficients for all relevant pressure-dependent reactions, including well-skipping pathways, are predicted using a combination of transition state theory and master equation simulations.
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