The concentrations of beryllium-7, sodium-22, aluminum-26, potassium-40, scandium-46, vanadium-48, chromium-51, manganese-54, cobalt-57, cobalt-60, and thorium-232 (thallium-208) have been measured in the Allende meteorite by nondestructive gamma-ray spectrometry. The high cobalt-60 content of the meteorite is indicative of a preatmospheric body with a minimum effective radius of 50 centimeters and a weight of 1650 kilograms; the aluminum-26 activity indicates a minimum exposure age of 3 million years.
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http://dx.doi.org/10.1126/science.166.3910.1269 | DOI Listing |
J Anal At Spectrom
January 2025
Institute for Geochemistry and Petrology, ETH Zürich Zürich Switzerland
This study presents a new procedure for high-precision Sm isotope analysis by thermal ionisation mass spectrometry (TIMS) for geological samples. A four-step chemical separation scheme results in sharp separation of Sm and Nd from the same sample aliquot. The first step utilises anion exchange resin to remove Fe from the sample solution.
View Article and Find Full Text PDFAstrobiology
December 2024
Solar System Exploration Division, NASA Goddard Space Flight Center, Greenbelt, Maryland, USA.
Chemistry
October 2024
Institute of Organic Chemistry, Laboratory for Sustainable Chemistry and Catalysis (LSusCat), Johannes Kepler University (JKU) Linz, Altenberger Straße, Linz, 694040, Austria.
This study explores the electrochemical properties of the carbonaceous Allende CV3 meteorite, focusing on its potential as a Fe-based catalyst derived from Mackinawite iron sulfide for electrocatalytic reactions facilitating nitrogen (N) fixation into ammonia. Through comprehensive analysis, we not only monitored the evolution of key compounds such as CN, sulfur/HS, H and carbonyl compounds, but also identified potential reagent carriers, indicating significant implications for the Strecker synthesis of amino acids in space environments. Initial examination revealed the presence of polypeptides, notably sequences including dimer Ala-α-HO-Gly, pentamer Gly-Ala, and hexamer Gly-(HO-Gly).
View Article and Find Full Text PDFNat Commun
May 2024
Department of Chemistry, University of Hawaii at Mānoa, Honolulu, HI, USA.
Chem Sci
May 2023
Department of Chemistry and Biochemistry, Florida International University Miami Florida 33199 USA
Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous in the interstellar medium and in meteorites such as Murchison and Allende and signify the missing link between resonantly stabilized free radicals and carbonaceous nanoparticles (soot particles, interstellar grains). However, the predicted lifetime of interstellar PAHs of some 10 years imply that PAHs should not exist in extraterrestrial environments suggesting that key mechanisms of their formation are elusive. Exploiting a microchemical reactor and coupling these data with computational fluid dynamics (CFD) simulations and kinetic modeling, we reveal through an isomer selective product detection that the reaction of the resonantly stabilized benzyl and the propargyl radicals synthesizes the simplest representative of PAHs - the 10π Hückel aromatic naphthalene (CH) molecule - the novel Propargyl Addition-BenzAnnulation (PABA) mechanism.
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