Dynamic mass spectrometer for studies of organic and inorganic molecules.

Anal Chim Acta

Institute of Electron Physics, Ukr. Nat. Acad. Sci., Department of Ion Processes, Universytetska Str. 21, 88017 Uzhhorod, Ukraine.

Published: July 2006

Experimental technique is described and relative cross-sections of direct and dissociative ionization of CO2, C4H9OH, C2H5OH, CH3OH, C6H12O6 and C7H8 molecules by electron impact in the near-threshold energy range are obtained. The experiment is performed on a setup with ion mass separation based on a monopole mass spectrometer which is proved to be successful for such a sort of experiments. For the incident electron energy range from 7 to 35 eV the energy dependences of cross-section of appearance of the main molecule ions and the fragment ions formed due to its dissociation are given.

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http://dx.doi.org/10.1016/j.aca.2005.11.055DOI Listing

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