It is shown that the previously characterized [Fe(III)(SR)(4)](1-) (R=Et, i-Pr, Ph) complexes can be synthesized by the direct reaction of 4equiv. of LiSR with FeCl(3) in DMF solution. [Fe(III)(SR)(4)](1-) complexes are synthetic analogs for the [Fe(III)(S-Cys)(4)] center in rubredoxin proteins.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2128701 | PMC |
| http://dx.doi.org/10.1016/j.jinorgbio.2007.07.004 | DOI Listing |
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