By employing superacidic fluoroantimonate ionic liquid (IL), [bmim][Sb(2)F(11)], as catalyst, not only thermodynamically-controlled but also kinetically-controlled Friedel-Crafts alkenylations of arenes with alkynes have been realized for the first time.
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Thermodynamically- and kinetically-controlled Friedel-Crafts alkenylation of arenes with alkynes using an acidic fluoroantimonate(v) ionic liquid as catalyst.
Chem Commun (Camb)
September 2007
Department of Chemistry, Institute of Basic Science, Sungkyunkwan University, Suwon 440-746, Korea.
By employing superacidic fluoroantimonate ionic liquid (IL), [bmim][Sb(2)F(11)], as catalyst, not only thermodynamically-controlled but also kinetically-controlled Friedel-Crafts alkenylations of arenes with alkynes have been realized for the first time.
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