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Versatile synthesis and mechanism of activation of S-benzoxazolyl glycosides. | LitMetric

Versatile synthesis and mechanism of activation of S-benzoxazolyl glycosides.

J Org Chem

Department of Chemistry and Biochemistry, University of Missouri-St. Louis, One University Boulevard, St. Louis, Missouri 63121, USA.

Published: August 2007

As a part of a program for developing new efficient procedures for stereoselective glycosylation, a range of S-benzoxazolyl (SBox) glycosides have been synthesized. The mechanistic aspects of the SBox moiety activation for glycosylation via a variety of conceptually different pathways in the presence of thiophilic, electrophilic, or metal-based promoters have been investigated.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2535574PMC
http://dx.doi.org/10.1021/jo0711844DOI Listing

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