A re-circulating filtration process using oxide-coated sand successfully removed COD and turbidity from log yard runoff. After passing only one pore volume of the runoff through the sand column, 72% COD was removed. The 2.4% Fe and Al oxide coating on the sand contributed to better COD removal than was obtained when the sand was stripped of oxide coating (86% versus 52%, respectively), at least initially before saturation of adsorption sites on the oxide coating occurred. The best COD removal performance came from conditioned sand. This sand, from the same original source and identical to the oxide-coated sand used in all experiments, came from an existing experimental sand column that had been treating log yard runoff for 1 year. The "conditioning" resulted in the sand having a higher TOC content (0.26% wt) and smaller particle sizes. This sand was able to consistently remove 80% COD from repeated batches of log yard runoff with strengths up to 3690 mg l(-1).
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http://dx.doi.org/10.1080/09593332808618842 | DOI Listing |
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