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Heterododecanuclear Pt(6)Ln(6) (Ln = Nd, Yb) arrays of 4-ethynyl-2,2'-bipyridine with sensitized near-IR lanthanide luminescence by Pt --> Ln energy transfer. | LitMetric
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Heterododecanuclear Pt(6)Ln(6) (Ln = Nd, Yb) arrays of 4-ethynyl-2,2'-bipyridine with sensitized near-IR lanthanide luminescence by Pt --> Ln energy transfer.

Hai-Bing Xu Li-Yi Zhang Zai-Lai Xie En Ma Zhong-Ning Chen

Chem Commun (Camb)

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.

Published: July 2007

Heterododecanuclear Pt(6)Ln(6) (Ln = Nd, Yb) complexes of 4-ethynyl-2,2'-bipyridine (HC[triple bond, length as m-dash]Cbpy), prepared using emissive Pt(Me(3)SiC[triple bond, length as m-dash]Cbpy)(C[triple bond, length as m-dash]Cbpy)(2) as an alkynyl bridging "ligand", afford sensitized near-infrared (NIR) lanthanide luminescence by Pt --> Ln energy transfer from both Pt(bpy)(acetylide)(2) and Pt(2)(dppm)(2)(acetylide)(2) chromophores.

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 Source
http://dx.doi.org/10.1039/b703135aDOI Listing

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