By use of a metallo-supramolecular concept, a linear iron(ii) coordination chain [Fe(II)(L)](n)(BF(4))(2n) (L = 1,4-bis(1,2':6',1''-bispyrazolylpyridin-4'-yl)benzene) was rationally designed and synthesized. The molecular chain shows a reversible spin transition at 323 K with a ca. 10 K wide hysteresis loop.
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| http://dx.doi.org/10.1039/b702468a | DOI Listing |
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