The existence of electrophoretic mobility at high electrolyte concentrations defines a remarkable peculiarity in the electrosurface characteristics of soft particles. According to Ohshima [H. Ohshima, Colloids Surf. 103 (1995) 249], this effect is caused by the electroosmotic flow within the soft particle shell. An explanation supporting Ohshima's conclusion can be derived from classic electrokinetic theories. Based on the Henry theory [D.C. Henry, Proc. R. Soc. London Ser. A 133 (1931) 106], we demonstrate that the electrophoretic mobility of soft particles does not disappear at decinormal concentration.
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http://dx.doi.org/10.1016/j.jcis.2007.04.072 | DOI Listing |
ACS Nano
January 2025
Soft Foundry Institute, Seoul National University, Seoul 08826, Republic of Korea.
Nickel-rich NCM cathode materials promise lithium-ion batteries with a high energy density. However, an increased Ni fraction in the cathode leads to complex phase transformations with electrode-electrolyte side reactions, which cause rapid capacity fading. Here, we show that an initial formation cycle at 0.
View Article and Find Full Text PDFEur Phys J E Soft Matter
January 2025
Department of Physics and Astronomy, McMaster University, 1280 Main Street West, Hamilton, ON, L8S 4M1, Canada.
We present a simple and inexpensive method for measuring weak cohesive interactions. This technique is applied to the specific case of oil droplets with a depletion interaction, dispersed in an aqueous solution. The experimental setup involves creating a short string of droplets while immobilizing a single droplet.
View Article and Find Full Text PDFMacromol Rapid Commun
January 2025
Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Straße 6, D-01069, Dresden, Germany.
Gold nanoparticles represent nanosized colloidal entities with high relevance for both basic and applied research. When gold nanoparticles are functionalized with polymer-molecule ligands, hybrid nanoparticles emerge whose interactions with the environment are controlled by the polymer coating layer: Colloidal stability and structure formation on the single particle level as well as at the supracolloidal scale can be enabled and engineered by tailoring the composition and architecture of this polymer coating. These possibilities in controlling structure formation may lead to synergistic and/or emergent functional properties of such hybrid colloidal systems.
View Article and Find Full Text PDFNanomicro Lett
January 2025
Department of Chemical Engineering, The Pennsylvania State University, University Park, PA, 16802, USA.
Plant cell wall (CW)-like soft materials, referred to as artificial CWs, are composites of assembled polymers containing micro-/nanoparticles or fibers/fibrils that are designed to mimic the composition, structure, and mechanics of plant CWs. CW-like materials have recently emerged to test hypotheses pertaining to the intricate structure-property relationships of native plant CWs or to fabricate functional materials. Here, research on plant CWs and CW-like materials is reviewed by distilling key studies on biomimetic composites primarily composed of plant polysaccharides, including cellulose, pectin, and hemicellulose, as well as organic polymers like lignin.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Soft Condensed Matter & Biophysics, Debye Institute for Nanomaterials Science, Utrecht University, Princetonplein 1, 3584 CC Utrecht, The Netherlands.
Since the influential work of ten Wolde, Ruiz-Montero, and Frenkel [Phys. Rev. Lett.
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