Ambient air concentrations of nitrous oxide (N2O) and volatile anesthetics were assessed under routine conditions in a total of 41 surgical suites located at seven Vienna hospitals. Continuous measurements were performed by means of infrared trace gas analyzers throughout a period of approximately 450 h. Additional analyses of ventilation facilities (if installed) revealed no essential deficiencies; however, anesthetic gas scavenging (AGS) systems yielded insufficient flow rates in 32% (less than 25 l/min). In surgical suites without mechanical ventilation or scavenging systems (2 out of 41), maximum occupational threshold limits (i.e., 100 ppm N2O; 5 ppm halothane) were exceeded continuously and to considerable degrees throughout the duration of anesthesia. During measurements conducted in operating rooms (ORs) in otolaryngology departments, extreme peaks (greater than 2600 ppm N2O, greater than 150 ppm halothane) of several minutes duration were documented when open-circuit anesthesia was performed. In the general surgical ORs equipped with modern ventilation facilities ambient air contamination was lowest, time-weighted average (TWA) values ranging from 8 to 15 ppm (mean 11 +/- 3 ppm) for N2O and 0.1 to 0.6 ppm (mean 0.3 +/- 0.2 ppm) for the halogenated anesthetic. Despite good ventilation and scavenging in the gynecological ORs, distinctly higher concentrations (mean 83 +/- 49, range 24-211 ppm N2O; mean 0.75 +/- 0.3, range 0.3 to 1.3 ppm volatile agent) were measured in cases where anesthesia was delivered by mask. TWA values exceeding currently established maximum workplace concentrations were found in an unscavenged but ventilated urological OR. At present, short-term concentration peaks seem to be inevitable even under optimal OR ventilation conditions.(ABSTRACT TRUNCATED AT 250 WORDS)
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J Air Waste Manag Assoc
January 2025
Graduate Institute of Environmental Engineering, National Central University, Taoyuan City, Taiwan.
In addition to selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR) which are available to remove NO from flue gas, oxidation method is receiving more and more attention because this method makes it possible to remove NO and SO from flue gas simultaneously by wet scrubbing. O as a strong oxidant has a high oxidation capacity and it can oxide NO to NO which has a higher water solubility compared with NO. However, it needs a long reaction time and the escape of unreacted ozone may cause secondary pollution.
View Article and Find Full Text PDFAnal Chem
September 2024
Anhui Institute of Optics and Fine Mechanics, HFIPS, Chinese Academy of Sciences, Hefei230031, China.
Greenhouse gas (GHG) detection plays an important role in climate change research and industry applications. A novel photoacoustic spectroscopy (PAS) sensor based on multiple resonators has been developed for the detection of GHGs. The major GHGs CO, CH, and NO were measured simultaneously using only one acoustic sensor by coupling three acoustic resonators into a photoacoustic cell.
View Article and Find Full Text PDFEnviron Sci Technol
August 2024
School of Chemistry and Chemical Engineering, Institution for Energy Research, Jiangsu University, Zhenjiang 212013, P. R. China.
Hitherto, sulfur poisoning and hydrothermal aging have still been the challenges faced in practical applications of the Cu-SSZ-13 catalyst for the selective catalytic reduction (SCR) of NO from diesel engine exhaust. Here, we elaborately design and conduct an in-depth investigation of the synthetic effects of hydrothermal aging and SO poisoning on pristine Cu-SSZ-13 and Cu-SSZ-13@CeZrO core@shell structure catalysts (Cu@CZ). It has been discovered that Cu@CZ susceptible to 750 °C with 5 vol % HO followed by 200 ppm SO with 5 vol % HO (Cu@CZ-A-S) could still maintain nearly 100% NO conversion across the significantly wider temperature region of 200-425 °C, which is remarkably broader than that of the Cu-SSZ-13-A-S (300-400 °C) counterpart.
View Article and Find Full Text PDFDalton Trans
July 2024
Department of Chemistry, Auckland University of Technology, Private Bag 92006, Auckland 1142, New Zealand.
Co(III) complexes of the N-heterocyclic carbene ligand PY4Im (PY4Im = (1,3-bis(bis(2-pyridyl)methyl)imidazol-2-ylidene)) having the general formula [(PY4Im)Co(X)](ClO) (X = NCMe; = 3: OH, N, NCS, ONO, F; = 2: OCO, = 1; (N), = 0) were prepared and structurally characterised. X-ray structural data are consistent with the presence of a influence due to the coordinated carbene carbon, and this is also supported by computational results. C NMR spectra of the complexes did not display peaks corresponding to the carbene carbon, except in the case of the [(PY4Im)Co(OCO)] cation, where a peak at = 170.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
School of Energy and Environmental Engineering, University of Science & Technology Beijing, Beijing Key Laboratory of Resource-oriented Treatment of Industrial Pollutants, Beijing 100083, China. Electronic address:
Generally, sulfur poisoning is considered to be one of the main factors contributing to the deactivation of selective catalytic reduction of NO by CO (CO-SCR) catalysts, while the promotional effect of SO on NO reduction over Ir/SiO is observed which is an interesting scientific phenomenon. After the introduction of 20 ppm SO, NO conversion increased from ∼ 40 % to ∼ 90 % at 275 °C, and N selectivity increased from ∼ 80 % to 100 % at 200 ∼ 300 °C. Furthermore, the promoting effect could remain unchanged after 24 h of continuous reaction.
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