Environ Sci Technol
Consortium for Fossil Fuel Science, University of Kentucky, 533 S. Limestone Street, Lexington, Kentucky 40506-0043, USA.
Published: May 2007
Determination and classification of quartz in coal fly ash (CFA) is a subject of interest because of the adverse health effects caused by inhalation of crystalline silica. Workers with prolonged exposure to this carcinogen can develop respiratory diseases over time. This obviously may include utility plant workers involved in the handling, loading, and hauling of CFA. In this investigation, computer-controlled scanning electron microscopy (CCSEM) and X-ray diffraction (XRD) were used to investigate Si-rich phases in CFA to develop a better approach for the determination of respirable quartz. Three CFA samples from utility boilers and a NIST standard CFA sample were investigated. The XRD measurements indicated that the four samples contained from 7.0 to 16.0 wt.% of quartz. The CCSEM measurements utilized both particle size distributions and a particle shape parameter, circularity, to classify the Si-rich phases in these ashes as either crystalline or amorphous (glass). The results indicated that the amount of free, respirable, quartz in these CFA samples ranged from only 0.1-1.0 vol % and showed little correlation with the XRD results for the bulk ash. These results are significant in view of the factthat XRD is the traditional method of measuring crystalline silica in dust collected from workplace atmospheres.
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http://dx.doi.org/10.1021/es062938j | DOI Listing |
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