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Formal chemoselective synthesis of leucascandrolide A. | LitMetric

Formal chemoselective synthesis of leucascandrolide A.

Org Lett

Laboratoire de Chimie Organique, ESPCI, CNRS, 10 Rue Vauquelin, 75231 Paris Cedex 05, France.

Published: June 2007

A chemoselective synthesis of the macrocyclic core of leucascandrolide A has been achieved, utilizing highly enantioselective allylmetalations, an enantioselective Noyori reduction of a propargylic ketone and olefin metatheses as the key steps.

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Source
http://dx.doi.org/10.1021/ol070670aDOI Listing

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