Formal chemoselective synthesis of leucascandrolide A. | LitMetric

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Formal chemoselective synthesis of leucascandrolide A. | LitMetric

Formal chemoselective synthesis of leucascandrolide A.

Laurent Ferrié Sébastien Reymond Patrice Capdevielle Janine Cossy

Org Lett

Laboratoire de Chimie Organique, ESPCI, CNRS, 10 Rue Vauquelin, 75231 Paris Cedex 05, France.

Published: June 2007

A chemoselective synthesis of the macrocyclic core of leucascandrolide A has been achieved, utilizing highly enantioselective allylmetalations, an enantioselective Noyori reduction of a propargylic ketone and olefin metatheses as the key steps.

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http://dx.doi.org/10.1021/ol070670a	DOI Listing

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