The combinative use of Au(I), a skeletally flexible diphosphine and a bifunctional spacer of pyridyl carboxylate with tunable directional and donor properties has resulted in a series of structurally distinctive ensembles and Au(2) metalloligands with O-donicity.
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University of Regensburg, Institute of Inorganic Chemistry 93040 Regensburg Germany
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E-35 Holmes Hall, Michigan State University, Lyman Briggs College, 919 E. Shaw Lane, East Lansing, MI 48825, USA.
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Departamento de Química Inorgánica, Facultad de Química, Universidad de Murcia, Campus de Espinardo 19, Murcia 30100, Spain.
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Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng, Henan 475004, P. R. China.
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