Advancements in natural abundance solid-state 33S MAS NMR: characterization of transition-metal M=S bonds in ammonium tetrathiometallates.

Chem Commun (Camb)

Instrument Centre for Solid-State NMR Spectroscopy, Department of Chemistry, University of Aarhus, DK-8000, Aarhus C, Denmark.

Published: April 2007

We report the first (33)S chemical shift anisotropy (CSA) data as obtained from a combined determination of (33)S CSA and quadrupole coupling parameters utilizing the observation of both the (33)S (I = 3/2) central and satellite transitions in a natural abundance (33)S MAS NMR study aimed at characterizing the two important tetrathiometallates (NH4)(2)MoS(4) and (NH4)(2)WS(4).

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Source
http://dx.doi.org/10.1039/b618497aDOI Listing

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