Interaction forces between colloidal particles in liquid: theory and experiment.

Adv Colloid Interface Sci

School of Chemical, Environmental and Mining Engineering, The University of Nottingham, University Park, Nottingham, NG7 2RD, UK.

Published: October 2007

AI Article Synopsis

  • Colloidal particles in suspensions interact through various forces, which significantly influence the properties of materials and industrial processes.
  • The review covers different types of colloidal forces, including London-van der Waals forces, electrical double layer forces, and steric forces, and discusses the DLVO theory for predicting total interaction forces.
  • Advanced measurement techniques, particularly atomic force microscopy (AFM) and surface force apparatus (SFA), have validated and improved existing theories about these interactions, aiding in the understanding of complex phenomena and improving industrial applications.

Article Abstract

The interaction forces acting between colloidal particles in suspensions play an important part in determining the properties of a variety of materials, the behaviour of a range of industrial and environmental processes. Below we briefly review the theories of the colloidal forces between particles and surfaces including London-van der Waals forces, electrical double layer forces, solvation forces, hydrophobic forces and steric forces. In the framework of Derjaguin-Landau-Verwey-Overbeek (DLVO) theory, theoretical predictions of total interparticle interaction forces are discussed. A survey of direct measurements of the interaction forces between colloidal particles as a function of the surface separation is presented. Most of the measurements have been carried out mainly using the atomic force microscopy (AFM) as well as the surface force apparatus (SFA) in the liquid phase. With the highly sophisticated and versatile techniques that are employed by far, the existing interaction theories between surfaces have been validated and advanced. In addition, the direct force measurements by AFM have also been useful in the explaining or understanding of more complex phenomena and in engineering the products and processes occurring in many industrial applications.

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Source
http://dx.doi.org/10.1016/j.cis.2007.04.003DOI Listing

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