The removal of bisphenol A (BPA) in drinking water was investigated by ultrafiltration membranes (UF) using dead-end stirred-cell filtration system. The experiment was focused on the effect of various factors on removal efficiency with respect to BPA initial concentration, molecular weight cut offs (MWCOs) of membrane, pH, ionic strength and organic matter. The results showed that UF could remove BPA effectively. UF with 2 000 - 10 000 MWCOs removed BPA by over 92%, with initial concentration of BPA ranging from 100 to 600 microg/L. As pH of solution approached the pK(a) of BPA (9.6 - 11.3), BPA removal efficiency dropped significantly. The effect of ionic strength on BPA removal was negligible. The influence of humic acid in solution on BPA removal was minor. It can be concluded that adsorption may play a significant role in UF process for removing hydrophobic molecular BPA.
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J Environ Manage
January 2025
Sanitary Engineering Laboratory, Department of Water Resources and Environmental Engineering, School of Civil Engineering, National Technical University of Athens, 9 Iroon Polytechniou St., Zographou Campus, 15773, Athens, Greece.
Vertical subsurface flow constructed wetlands (VSSF CWs) were employed to investigate the use of biochar that could be produced with local agricultural biomass through pyrolysis, recycled glass from local recycling companies and gel beads with decreased packing volume and shipping cost as substrate alternatives to sand. The materials were assessed in terms of granulometry, porosity, adsorption capacity and hydraulic conductivity and were used for the treatment of an upflow anaerobic sludge blanket (UASB) reactor, treating domestic wastewater, effluent. Granulometry was a major factor impacting TSS removal that ranged from 81% ± 10% to 97% ± 2%.
View Article and Find Full Text PDFEcotoxicol Environ Saf
January 2025
Institute of Pharmaceutical and Biomaterials, Lianyungang Normal College, Sheng Hu Lu 28, Lianyungang 222006, China. Electronic address:
Bisphenol A (BPA), a well-known endocrine-disrupting chemical, has garnered significant attention in environmental science and policy. BPA can enter the aquatic environment through different routes, posing potential risks even at a low concentration. In this study, a four-compartment system [water, sediment, biota (zebrafish), and submerged aquatic vegetation (Vallisneria natans)] of a point source continuous discharge microcosm was established to investigate the distribution and fate of BPA in an aquatic microcosm.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Chemical Engineering, Toronto Metropolitan University 350 Victoria Street, Toronto, Ontario M5B 2K3, Canada. Electronic address:
The presence of endocrine disrupting chemicals (EDCs) in water can impart detrimental effects on public health by mimicking the behaviors of natural hormones and their associated receptors in human body. Studies have demonstrated that ligninolytic enzymes such as laccase can degrade various phenolic compounds, including a broad range of EDCs. In this study, the technique of covalent immobilization of laccase through carbodiimide coupling chemistry on highly adsorptive reduced graphene oxide (rGO) sponges was utilized to effectively remove two representative EDCs; namely, bisphenol A (BPA) and triclosan (TCS) from water.
View Article and Find Full Text PDFEnviron Res
January 2025
State Key Laboratory of Marine Pollution and Department of Chemistry, City University of Hong Kong, Tat Chee Avenue, Hong Kong, Kowloon, 999077, China; School of Energy and Environment, City University of Hong Kong, Tat Chee Avenue, Hong Kong, Kowloon, 999077, China.
Bisphenol A (BPA) is a commonly used endocrine-disrupting chemical found in high levels in wastewater worldwide. Aerobic denitrification is a promising alternative to conventional nitrogen removal processes. However, the effects of BPA on this novel nitrogen removal process have rarely been reported.
View Article and Find Full Text PDFDrug Dev Ind Pharm
January 2025
Institute of Pharmaceutics, College of Pharmaceutical Sciences, Zhejiang University, Hangzhou, China.
Objective: Boron Neutron Capture Therapy (BNCT) is a novel precision radiotherapy. The key to BNCT application lies in the effective targeting and retention of the boron-10 (B) carrier. Among the various compounds studied in clinical settings, 4-boronophenylalanine (BPA) become the most prevalent one currently.
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