Chromite ore processing residue (COPR), derived from the so-called high-lime processing of chromite ore, contains a significant fraction of a leachable Cr(VI) which is harmful to human being and other organisms. In recent years, the concern over environmental pollution from the waste residue containing Cr(VI) has become a major problem for the chromium chemical industry. The main purpose of this investigation is to evaluate a new method for remediation of Cr(VI) in COPR. COPR was mixed with reductants, sucrose, starch or flour, and was calcinated at elevated temperatures in inertial gas. Effects of temperature, dosages of reductants and time on Cr(VI) reduction were investigated. Above 500 degrees C, Cr(VI) can be completely reduced to Cr(III).
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http://dx.doi.org/10.1016/j.jhazmat.2007.04.009 | DOI Listing |
RSC Adv
June 2024
School of Safety Science and Engineering, Anhui University of Science and Technology Huainan 232001 China
Chromite ore processing residue (COPR) is a typical hazardous waste, which contains Cr(vi) and poses a great threat to the ecological environment and human health. In this study, solidification/stabilization (S/S) of COPR was carried out by using blast furnace slag (BFS) and fly ash (FA) to prepare alkali-activated cementitious materials (AACM). The influence of different factors (water glass modulus, liquid-solid ratio, alkali-solid content and curing temperature) on compressive strength was investigated by single-factor experiment.
View Article and Find Full Text PDFChemosphere
June 2024
Department of Mining Engineering, Amirkabir University of Technology, Tehran, Iran.
This research investigates the adsorption potential of chrysotile and lizardite, two minerals derived from chromite ore wastes, for the uptake of Methylene Blue (MB) dye from waste streams. The characterization of these minerals involves XRD, XRF, FTIR, and SEM. Results confirm the dominance of polymorphic magnesium silicate minerals, specifically chrysotile and lizardite, in the samples.
View Article and Find Full Text PDFACS Eng Au
February 2024
CanmetMINING, Natural Resources Canada, 555 Booth Street, Ottawa, ON K1A 0G1, Canada.
Direct reduction of chromite (DRC) is a promising alternative process for ferrochrome production with the potential to significantly reduce energy consumption and greenhouse gas emissions compared to conventional smelting. In DRC, chromium (Cr) and iron (Fe) from chromite ore incongruently dissolve into a molten salt, which facilitates mass transfer to a carbon (C) reductant where in situ metallization occurs. Consequently, ferrochrome is produced below the slag melting temperatures, achieving substantial energy savings relative to smelting.
View Article and Find Full Text PDFJ Hazard Mater
April 2024
Catalytic Reaction Engineering Laboratory, Department of Chemical Engineering, Indian Institute of Technology (IIT) Delhi, Hauz Khas, New Delhi 110016, India; Indian Institute of Technology (IIT) Roorkee, Roorkee, Uttarakhand 247667, India.
Rania-Khan Chandpur site, (Kanpur Dehat, Uttar Pradesh, India), one of the highly Chromium (Cr) contaminated sites in India due to Chromite Ore Processing Residue (COPR), has been investigated at the field-scale. We found that the area around the COPR dumps was hazardously contaminated with the Cr where its concentrations in the surface water and groundwater were > 40 mgL, its maximum contents in the COPRs and in the soils of the adjoining lands were 9.6 wt% and 3.
View Article and Find Full Text PDFRSC Adv
January 2024
State Key Laboratory of Coal Mine Disaster Dynamics and Control, Chongqing University Chongqing 400044 China
Chromite ore processing residue (COPR) is a hazardous waste because of leachable chromium, especially Cr(vi). Therefore, ascorbic acid (AA) and blast furnace slag (BFS) have been used to detoxify and solidify COPR. On this basis, environmental stability experiments with high temperature and freeze-thaw cycles were carried out to explore the stability performance of a solidified body with 40% COPR.
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