AI Article Synopsis
- The study examines how different types of sulfoxides affect the allylation of benzoyl hydrazone with allyl trichlorosilane.
- It focuses on three types of compounds: monosulfoxides, methylene-bridged C2-symmetric bissulfoxides, and ethylene-bridged C2-symmetric bissulfoxides.
- Results indicate that both the type of spacer between the sulfinyl groups and the concentration of the reaction influence the enantioselectivity of the process.
Article Abstract
A comparative study on the allylation of a benzoyl hydrazone with allyl trichlorosilane using monosulfoxides, methylene-bridged C2-symmetric bissulfoxides, and ethylene-bridged C2-symmetric bissulfoxides shows that the enantioselectivity of the process is highly dependent on the spacer between the two sulfinyl sulfurs and the concentration of the reaction.
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| http://dx.doi.org/10.1021/ol070729d | DOI Listing |
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Article Synopsis
- The study examines how different types of sulfoxides affect the allylation of benzoyl hydrazone with allyl trichlorosilane.
- It focuses on three types of compounds: monosulfoxides, methylene-bridged C2-symmetric bissulfoxides, and ethylene-bridged C2-symmetric bissulfoxides.
- Results indicate that both the type of spacer between the sulfinyl groups and the concentration of the reaction influence the enantioselectivity of the process.
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