Reaction of [Ir(PPh(3))(2)(COD)][BAr(F)(4)] with H(2) in dichloroethane solution results in [Ir(PPh(3))(2)(H)(2)(ClCH(2)CH(2)Cl)][BAr(F)(4)], which has been fully characterised by X-ray crystallography, NMR spectroscopy and ESI-MS. Its activity towards alkene hydrogenation has been compared with analogous CH(2)Cl(2) complexes.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/b702399e | DOI Listing |
Publication Analysis
Top Keywords
[irpph32h2clch2ch2cl][barf4] well
4
well characterised
4
characterised transition
4
transition metal
4
metal dichloroethane
4
dichloroethane complex
4
complex reaction
4
reaction [irpph32cod][barf4]
4
[irpph32cod][barf4] dichloroethane
4
dichloroethane solution
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!