Kevlar and Nomex are high-performance polymers which have wide varieties of applications in daily life. Recently, they have been proposed to be biocidal materials when reacted with household bleach (sodium hypochlorite solution) because they contain amide moieties which can be chlorinated to generate biocidal N-halamine functional groups. Although Nomex can be chlorinated without any significant decomposition, Kevlar decomposes under the same chlorination conditions. In this study, two mimics for each of the polymers were synthesized to simulate the carboxylate and diaminophenylene components of the materials. It was found that the p-diaminophenylene component of the Kevlar mimic is oxidized to a quinone-type structure upon treatment with hypochlorous acid, which then decomposes. However, such a mechanism for the Nomex mimic is not possible. In this paper, based upon these observations, a plausible answer will be provided to the title question.
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http://dx.doi.org/10.1021/jp070586c | DOI Listing |
Materials (Basel)
January 2025
Key Laboratory of Testing Technology for Manufacturing Process of Ministry of Education, Southwest University of Science and Technology, Mianyang 621010, China.
ACS Appl Mater Interfaces
January 2025
Intelligent Polymer Research Institute, Faculty of Engineering and Information Sciences, Innovation Campus, University of Wollongong, Wollongong, NSW 2500, Australia.
Textile-based lithium-ion batteries (LIBs) are in great demand to power wearable electronics. They currently face a key safety challenge, particularly concerning mechanical abuse that could trigger thermal runaway, causing harm to individuals. Here, we report on Kevlar-fabric-based LIBs that can afford high impact tolerance while offering excellent electrochemical performance comparable to metal-foil-based cells.
View Article and Find Full Text PDFProg Addit Manuf
May 2024
College of Science and Engineering, University of Galway, Galway, Ireland.
This paper investigates the performance of continuous fibre-reinforced 3D printed components in salt water medium at room temperature. Markforged Mark Two 3D printer was employed to fabricate standard specimens made of Onyx and reinforced Onyx specimens with continuous carbon, high-strength high-temperature glass, and Kevlar fibres. Aging process was conducted to characterize the long-term effect of salt water on the mechanical behaviour of fibre-reinforced 3D printed samples.
View Article and Find Full Text PDFPolymers (Basel)
November 2024
Yantai Research Institute, Harbin Engineering University, Yantai 264000, China.
The poor interlaminar fracture toughness is a critical limiting factor for the structural applications of aramid fiber/epoxy resin composites. This study investigates the effects of laser-induced graphene (LIG) and short Kevlar fibers on the interfacial toughness and damage detection of aramid composite materials. Mode II tests and tensile tests were conducted to evaluate mechanical properties and damage detection using the piezoresistive characteristics of LIG.
View Article and Find Full Text PDFHeliyon
October 2024
Portsmouth Centre for Advanced Materials and Manufacturing (PCAMM), School of Electrical and Mechanical Engineering, University of Portsmouth, PO1 3DJ, Hampshire, United Kingdom.
Current research uses a novel recycled milled carbon (rmCF), recycled milled Kevlar (rmKF), and innovative Hybrid fillers (rmHF) of both to increase glass/epoxy composite laminate delamination resistance. This study examines how crack propagation and fibre orientation affect laminated composite delamination fracture toughness. Recycled milled Fillers in the interlayer increase stiffness, delamination resistance, and fracture toughness by increasing the energy needed to crack the interlaminar domain.
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