Stramonita haemastoma was investigated as a suitable bioindicator of TBT and TPhT contamination in the tropical Atlantic Ocean by: 1. Imposex induction in healthy females after inoculation with TBT and TPhT in the laboratory; and 2. Determining incidence of imposex in S. haemastoma collected from areas with various levels of tributyltin (TBT) and triphenyltin (TPhT) and determining the concentrations of these chemical in its tissues and that of its prey, the mussell Perna pernas. Imposex intensities and organotin concentrations in tissues showed good correlation, indicating S. haemastoma as a reliable bioindicator of TBT and TPhT contamination in coastal waters. Body burden threshold of TBT and TPhT for imposex induction was estimated to be 10-20 ng g(-1).
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http://dx.doi.org/10.1016/j.marenvres.2007.03.001 | DOI Listing |
Water Res
December 2024
Programa de Pós-Graduação em Química Tecnológica e Ambiental (PPGQTA), Universidade Federal do Rio Grande (FURG), Rio Grande, RS 96203-900, Brazil; Instituto de Oceanografia, Universidade Federal do Rio Grande (IO-FURG), Av. Itália s/n, Rio Grande, RS 96203-900, Brazil. Electronic address:
Organotin compounds (OTs) used to be the most widely used biocide in antifouling paint systems, but the International Maritime Organization (IMO) banned them because of their high environmental toxicity to non-target organisms. Currently, at least 25 active ingredients are being employed as biocides in antifouling paint formulations. In the present study, silicone rubber-based passive sampling was used to determine the freely dissolved concentrations (C) of 6 OTs and 4 booster biocides in the water column at the entrance of Santos Port's main navigation channel, the largest Port of South America (southeastern Brazil).
View Article and Find Full Text PDFEnviron Pollut
December 2024
Environmental Chemistry Research Group, School of Exact and Natural Sciences, Chemistry Program, Campus of San Pablo, University of Cartagena, Carrera 50 No. 24-99, Cartagena, 130015, Colombia.
Organotin compounds (OTCs), such as tributyltin (TBT) and triphenyltin (TPhT), are released in aquatic environments from antifouling coatings and can cause imposex, an abnormal condition where female snails develop male sexual characteristics. This study investigates temporal variations in imposex incidence along the Colombian Caribbean coast following the 2008 global ban on TBT-based antifouling paints. Over a 12-year period, we assessed imposex in 1,384 adults snails from six species (58% female and 42% male) during 2012, 2016, and 2023.
View Article and Find Full Text PDFChemosphere
August 2024
Programa de Pós-Graduação em Química Tecnológica e Ambiental (PPGQTA), Escola de Química e Alimentos (EQA), Universidade Federal do Rio Grande - FURG, 96203-900, Rio Grande, RS, Brazil; Instituto de Oceanografia, Universidade Federal do Rio Grande (IO-FURG), Av. Itália s/n, Campus Carreiros, 96203-900, Rio Grande, RS, Brazil. Electronic address:
Organotin compounds (OTs) are well studied in various environmental compartments, with a critical focus on the water column as their primary entry point into aquatic ecosystems. In this context, a method for the analysis of organotin (OTs) in water using silicone rubber-based passive sampling was optimized, validated, and field-tested. Validation covered crucial parameters, including the limit of detection (LOD), limit of quantification (LOQ), accuracy, precision, linearity, and matrix effect.
View Article and Find Full Text PDFJ Chromatogr A
March 2024
Institute for Occupational Safety and Health (IFA) of the German Social Accident Insurance, Alte Heerstraße 111, 53757, Sankt Augustin, Germany.
Organotin compounds (OTCs) are widely regulated but rank among the most used organometallic compounds in various industrial sectors. They are significantly more toxic than inorganic tin compounds. At workplaces, OTCs can be released as vapors or dust particles and can be absorbed by inhalation or skin contact.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
December 2023
Key Laboratory of the Three Gorges Reservoir Region's Eco-Environment, Ministry of Education, Chongqing University, Chongqing, 400045, China.
Organotin compounds (OTs) accumulate in fish easily, however, research on their influencing factors is still limited. This study collected 25 species of fish with different diets, habitats, and age from the Three Gorges Reservoir (TGR), the largest deep-water river channel-type reservoir in China, and analyzed the accumulation characteristics of OTs in these fish. The results showed that tributyltin (TBT) and triphenyltin (TPhT) were the dominant OTs in fish from the TGR.
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