The quest to create superhard materials rarely strays from the use of high-pressure synthetic methods, which typically require gigapascals of applied pressure. We report that rhenium diboride (ReB2), synthesized in bulk quantities via arc-melting under ambient pressure, rivals materials produced with high-pressure methods. Microindentation measurements on ReB2 indicated an average hardness of 48 gigapascals under an applied load of 0.49 newton, and scratch marks left on a diamond surface confirmed its superhard nature. Its incompressibility along the c axis was equal in magnitude to the linear incompressibility of diamond. In situ high-pressure x-ray diffraction measurements yielded a bulk modulus of 360 gigapascals, and radial diffraction indicated that ReB2 is able to support a remarkably high differential stress. This combination of properties suggests that this material may find applications in cutting when the formation of carbides prevents the use of traditional materials such as diamond.
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http://dx.doi.org/10.1126/science.1139322 | DOI Listing |
Nanoscale Horiz
March 2024
Department of Chemistry and Biochemistry, University of California, Los Angeles (UCLA), Los Angeles, CA 90095, USA.
The superhard ReB system is the hardest pure phase diboride synthesized to date. Previously, we have demonstrated the synthesis of nano-ReB and the use of this nanostructured material for texture analysis using high-pressure radial diffraction. Here, we investigate the size dependence of hardness in the nano-ReB system using nanocrystalline ReB with a range of grain sizes (20-60 nm).
View Article and Find Full Text PDFMaterials (Basel)
April 2020
Department of Physics, University of Alabama at Birmingham (UAB), Birmingham, AL 35294, USA.
An emerging class of superhard materials for extreme environment applications are compounds formed by heavy transition metals with light elements. In this work, ultrahigh pressure experiments on transition metal rhenium diboride () were carried out in a diamond anvil cell under isothermal and non-hydrostatic compression. Two independent high-pressure experiments were carried out on for the first time up to a pressure of 241 GPa (volume compression = 0.
View Article and Find Full Text PDFACS Nano
September 2019
Department of Chemistry and Biochemistry , UCLA , Los Angeles , California 90095-1569 , United States.
Rhenium diboride is an established superhard compound that can scratch diamond and can be readily synthesized under ambient pressure. Here, we demonstrate two synergistic ways to further enhance the already high yield strength of ReB. The first approach builds on previous reports where tungsten is doped into ReB at concentrations up to 48 at.
View Article and Find Full Text PDFJ Am Chem Soc
November 2016
Department of Mechanical and Nuclear Engineering, Virginia Commonwealth University, Richmond, Virginia 23284, United States.
Rhenium diboride (ReB), containing corrugated layers of covalently bonded boron, is a superhard metallic compound with a microhardness reaching as high as 40.5 GPa (under an applied load of 0.49 N).
View Article and Find Full Text PDFJ Acoust Soc Am
May 2010
National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA.
The five independent moduli required to construct the complete monocrystal elastic modulus tensor of the hexagonal-symmetry superhard compound ReB(2) were measured from 308 to 5 K using resonant ultrasound spectroscopy on a special-texture polycrystal. This is possible because, confirmed by X-ray diffraction, the specimen measured was composed of grains with hexagonal axes parallel so that its polycrystal elastic response is identical to a monocrystal and because hexagonal-symmetry solids are elastically isotropic in the plane perpendicular to the hexagonal axis. Along the hexagonal (c) axis, C(33) (0) = 1021 GPa, nearly equal to C(11) of diamond, and consistent with the superhard properties.
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