The Diels-Alder reaction between a quinone monoimine and cyclic diene allows for the construction of substituted carbazoles in a regiospecific manner. This methodology has sucessfully been employed in a divergent strategy, culminating in the synthesis of eustifolines A-D and glycomaurrol.
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Total synthesis of eustifolines A-D and glycomaurrol via a divergent Diels-Alder strategy.
Org Lett
May 2007
Department of Chemistry, The University of Western Ontario, London, Ontario, Canada.
The Diels-Alder reaction between a quinone monoimine and cyclic diene allows for the construction of substituted carbazoles in a regiospecific manner. This methodology has sucessfully been employed in a divergent strategy, culminating in the synthesis of eustifolines A-D and glycomaurrol.
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