1,3-Dimethylimidazolium-2-carboxylate and carbonic acid have been used to prepare a 1,3-dimethylimidazolium hydrogen carbonate salt by means of a Krapcho reaction. The ability to form hydrogen carbonate azolium salts allows for them to be used as precursors for fast, efficient, environmentally benign, and halide-free syntheses of many ionic liquids by a simple, acid-base reaction of virtually any acid (inorganic, organic, and organic noncarboxylic) with a pK(a) less than that of HCO(3) (-). Additionally, the kinetics of this reaction can be accelerated by employing catalytic amounts of DMSO (a traditional Krapcho solvent used in decarboxylation reactions) to catalyze the decarboxylation. The crystal structure of 1,3-dimethylimidazolium hydrogen carbonate monohydrate is the first example of an imidazolium-based hydrogen carbonate salt. There is a strong 2D hydrogen-bonded network with facially pi-stacked imidazolium cations located in the cavities created by this framework.
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