In the near-infrared and visible bandpasses optical propagation theory conventionally assumes that humidity does not contribute to the effects of atmospheric turbulence on optical beams. While this assumption may be reasonable for dry locations, we demonstrate that there is an unequivocal effect owing to the presence of humidity upon the strength of turbulence parameter, C(n)(2), from data collected in the Chesapeake Bay area over 100 m length horizontal propagation paths. We describe and apply a novel technique, Hilbert phase analysis, to the relative humidity, temperature, and C(n)(2) data to show the contribution of the relevant climate variable to C(n)(2) as a function of time.
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http://dx.doi.org/10.1364/ao.46.002453 | DOI Listing |
This study investigates the propagation characteristics of four-petal Gaussian beams through Cassegrain optical systems. With the properties of this new type of beam, the problem of masking loss in the Cassegrain optical system can be well solved. Analytical expressions of the optical field for beams after propagating the optical system are derived, considering atmospheric turbulence effects and random jitter on coupling efficiency.
View Article and Find Full Text PDFTalanta
December 2024
School of Chemical Engineering, Guizhou Minzu University, Guiyang, 550025, PR China.
Abnormal homocysteine (Hcy) levels in human serum have been associated with serious or vital diseases, making the reliable and easy detection of Hcy important to clinical analysis and biological study. In this work, five phosphorescent Ir(C^N)(N^N) complexes (Ir) having aldehyde group were synthesized as probes (C^N and N^N denoted ligands). A discussion was conducted on their molecular structure, electronic structure, photophysical parameters, and Hcy sensing ability, revealing the correlations between their molecular structures and performances.
View Article and Find Full Text PDFJ Comput Chem
December 2024
Instituto de Química, Universidade Federal do Rio de Janeiro, Cidade Universitária, CT, Rio de Janeiro, Brazil.
Cationic species, previously detected from ion-induced desorption of solid methane by plasma desorption mass spectrometry (PDMS), and neutral species, are investigated using high-level ab-initio approaches. From a set of 25 cationic and 26 neutral structures belonging to CH (n = 2-6) families, it was obtained the energy, rotational constants, harmonic vibrational frequency, charge distribution and excitation energies. The ZPVE-corrected energies, at CCSD(T)-F12; CCSD(T)-F12/RI/(cc-pVTZ-F12, cc-pVTZ-F12-CABS, cc-pVQZ/C) (n = 2-5) and CCSD(T)/cc-pVTZ (n = 6) levels, reveal that the topology of the most stable isomer vary with n and the charge.
View Article and Find Full Text PDFJ Cannabis Res
May 2024
Department of Clinical Biochemistry and Pharmacology, Ben-Gurion University of the Negev, Beer-Sheva, Israel.
Introduction: Multiple sclerosis (MS) is a chronic autoimmune disease of the central nervous system characterized by neuroinflammation, demyelination and axonal loss. Cannabis, an immunomodulating agent, is known for its ability to treat MS effectively. However, due to variations in the profile of secondary metabolites, especially cannabinoids, among cannabis cultivars, the effectiveness of cannabis treatment can vary, with significant variability in the effects on different biological parameters.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
July 2024
Jilin Engineering Normal University, College of Biological and Food Engineering, No.3050 Kaixuan Road, Changchun City, Jilin Province 130052, PR China.
The low cost and simple detection method for Hcy (homocysteine) is highly desired in analytical and biological fields since Hcy has been regarded as a bio-marker for multiple diseases. In this work, five Ir(C^N)(N^N) compounds having -CHO group in their C^N or N^N ligand were synthesized and tried for Hcy sensing. Electron-donating groups such as -NH and -CH were incorporated into the C^N or N^N ligand.
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