The title compound, [Zn(SO(4))(C(12)H(10)N(2))](n), features a layered structure based on [Zn(SO(4))](n) spirals linked by 1,2-di-4-pyridylethylene (bpe) ligands, with the tetrahedral Zn and S atoms lying on twofold axes. The bpe ligands are centrosymmetric. The layers are linked by weak C-H...O interactions.
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http://dx.doi.org/10.1107/S0108270107007123 | DOI Listing |
Clin Exp Med
September 2024
Department of Thoracic Surgery, Comprehensive Cancer Center Vienna, Medical University of Vienna, Vienna, Austria.
PD-1 (programmed cell death protein-1)/PD-L1 (programmed cell death ligand 1) as well as IL-10 (interleukin-10)/IL-10R (interleukin-10 receptor) interactions play a major role in tumor immune evasion in various malignancies. Several studies investigated the expression of PD-1 on T lymphocytes in pleural effusions (PE) in patients with malignant diseases. However, results in malignant pleural effusions (MPE) compared to benign PE (BPE) are underreported.
View Article and Find Full Text PDFInorg Chem
September 2024
College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, P.R. China.
Metal-organic frameworks (MOFs) have emerged as promising candidates for electrochemical energy storage and conversion due to their high specific surface areas, abundant active sites, and excellent chemical and structural tunability. However, the direct utilization of MOFs as electrochemical materials is a challenge because of the poor electroconductivity induced by the insulating nature of most organic linkers. Herein, a conjugated three-dimensional Ni-MOF {Ni(HBTC)(BPE)} () with a 2-fold interpenetrating structure was developed via the coordination polymerization of Ni, a HBTC ligand (1,3,5-benzenetricarboxylic acid), and a vinyl-functionalized bipyridine linker (1,2-di(4-pyridyl)ethylene, BPE).
View Article and Find Full Text PDFACS Sens
August 2024
College of Petrochemical Technology, Lanzhou University of Technology, 730050 Lanzhou, PR China.
Comput Methods Programs Biomed
October 2024
Institute of Physiology, Medical University of Innsbruck, Innsbruck, Austria; Omiqa Bioinformatics GmbH, Berlin, Germany.
Background And Objectives: Patch-Clamp recordings allow for in depth electrophysiological characterization of single cells, their general biophysical properties as well as characteristics of voltage- and ligand-gated ionic currents. Different acquisition modes, such as whole-cell patch-clamp recordings in the current or voltage clamp configuration, capacitance measurements or single channel recordings from cultured cells as well as acute brain slices are routinely performed for these purposes. Nevertheless, multipurpose transparent and adaptable software tools to perform reproducible state-of-the-art analysis of multiple experiment types and to manage larger sets of experimental data are currently unavailable.
View Article and Find Full Text PDFDalton Trans
August 2024
Key Laboratory of Cluster Science of Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, P. R. China.
The 1D homochiral coordination polymer (CP-1) {[Co(dTMP)(bpe)(HO)]·9HO} was constructed by using 2'-deoxy thymidine 5'-monophosphate disodium salt (dTMP·2Na), and auxiliary ligand bpe (1,2-bis(4-pyridyl)ethene) and characterized by single-crystal XRD, PXRD, IR, UV-visible, CD and TGA analyses. Molecular simulations revealed the selective chiral behaviour of CP-1 towards phenylalanine and histidine, as indicated by their higher binding free energies compared to other amino acids. Theoretical parameters were also compared with experimental UV-visible verdicts.
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