We have developed a source of cold LiH molecules for Stark deceleration and trapping experiments. Lithium metal is ablated from a solid target into a supersonically expanding carrier gas. The translational, rotational, and vibrational temperatures are 0.9+/-0.1, 5.9+/-0.5, and 468+/-17 K, respectively. Although they have not reached thermal equilibrium with the carrier gas, we estimate that 90% of the LiH molecules are in the ground state, X (1)Sigma(+)(v=0,J=0). With a single 7 ns ablation pulse, the number of molecules in the ground state is 4.5+/-1.8 x 10(7) molecules/sr. A second, delayed, ablation pulse produces another LiH beam in a different part of the same gas pulse, thereby almost doubling the signal. A long pulse, lasting 150 micros, can make the beam up to 15 times more intense.
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http://dx.doi.org/10.1063/1.2711434 | DOI Listing |
Phys Rev Lett
December 2024
The Engineering Faculty, Bar-Ilan University, Ramat-Gan 52900, Israel.
Quantum computing is currently hindered by hardware noise. We present a freestyle superconducting pulse optimization method, incorporating two-qubit channels, that enhances flexibility, execution speed, and noise resilience. A minimal 0.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2025
School of Physics, Dalian University of Technology, Dalian 116000, China. Electronic address:
Vibrational ladder climbing (VLC) is one of the advanced methods for achieving molecular dissociation, usually requires the use of chirped laser pulses to adapt to the change of energy difference between molecular vibrational levels. In this work, a scheme is proposed for using non-chirped pulses to couple the vibrational rotational levels of excited state to realize VLC dissociation of LiH molecules in the excited state. The first pulse induces population excitation to the excited state AΣ, while the second pulse is used to drive the excited state vibrational levels population up step by step until dissociation occurs.
View Article and Find Full Text PDFJ Chem Phys
November 2024
Fachbereich für Chemie und Physik der Materialien, Paris-Lodron Universität Salzburg, Jakob-Harringerstr. 2a, A-5020 Salzburg, Austria.
A method for the calculation of divergenceless, magnetically induced quantum mechanical current densities in molecules that approximates the exact current is presented. This was achieved by adding to the calculated conventional current density, i.e.
View Article and Find Full Text PDFJ Phys Chem A
October 2024
Department of Chemistry and Biochemistry, University of Arizona, Tucson, Arizona 85721, United States.
Low-lying rotationless states of the lithium hydride molecule are studied in the framework of the variational method without assuming the Born-Oppenheimer (BO) approximation. Highly accurate solutions to the six-particle (two nuclei and four electrons) Schrödinger equation are obtained by means of expanding the wave functions of the considered states in terms of many thousands of all-particle explicitly correlated Gausssians. The basis functions are optimized independently for each state using the analytic energy gradient with respect to the nonlinear parameters.
View Article and Find Full Text PDFJ Chem Phys
October 2024
Department of Chemistry and Engineering Research Center of Advanced Rare-Earth Materials of Ministry of Education, Tsinghua University, Beijing 100084, China.
The matrix product state (MPS) Ansatz offers a promising approach for finding the ground state of molecular Hamiltonians and solving quantum chemistry problems. Building on this concept, the proposed technique of quantum circuit MPS (QCMPS) enables the simulation of chemical systems using a relatively small number of qubits. In this study, we enhance the optimization performance of the QCMPS Ansatz by employing the variational quantum imaginary time evolution (VarQITE) approach.
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