The adsorption on powdered activated carbon (PAC) of ecotoxic or potentially ecotoxic micropollutants (ten pharmaceuticals, four X-ray contrast media, and eight industrial chemicals) present in a biologically treated municipal wastewater is studied. All but the X-ray contrast media are eliminated with high efficiency at an economically feasible PAC dosage of 10 mg/L. Based on the experimental data, the competition between the background organic matter and the micropollutant for the active sites of the adsorbent is modeled with the help of the adsorption and tracer analysis supported by the Ideal Adsorption Solution Theory. With granulated activated carbon, adsorption isotherms are determined by spiking. Based on these experimental data and modeled parameters, a lay-out of fixed-bed adsorbers may be simulated.
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http://dx.doi.org/10.1021/es0618595 | DOI Listing |
Inorg Chem
December 2024
Textile Pollution Controlling Engineering Center of Ministry of Ecology and Environment, College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China.
Carbon capture and storage (CCS) from dilute sources is an important strategy for stabilizing the concentration of atmospheric carbon dioxide and global temperature. However, the adsorption process is extremely challenging due to the sluggish diffusion rate of dilute CO. Herein, -phthalic acid (PTA)-derived hierarchical porous activated carbon (PTA-C) with abundant micro- and mesopores was successfully prepared for dilute CO (2 vol %) capture at ambient conditions.
View Article and Find Full Text PDFToxins (Basel)
December 2024
College of Life and Environmental Sciences, Hunan University of Arts and Science, Changde 415000, China.
Microcystin-leucine arginine (MC-LR) poses a serious threat to aquatic animals during cyanobacterial blooms. Recently, biochar (BC), derived from rice straw, has emerged as a potent adsorbent for eliminating hazardous contaminants from water. To assess the joint hepatotoxic effects of environmentally relevant concentrations of MC-LR and BC on fish, male adult zebrafish () were sub-chronically co-exposed to varying concentrations of MC-LR (0, 1, 5, and 25 μg/L) and BC (0 and 100 μg/L) in a fully factorial experiment.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
School of Instrument and Electronics, North University of China, Taiyuan 030051, China.
In order to broaden the working voltage (1.23 V) of aqueous supercapacitors, a high-performance asymmetric supercapacitor with a working voltage window reaching up to 2.1 V is assembled using a nanorod-shaped molybdenum trioxide (MoO) negative electrode and an activated carbon (AC) positive electrode, as well as a sodium sulfate-ethylene glycol ((NaSO-EG) electrolyte.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
Center for Genomics and Precision Medicine, Institute of Bioscience and Technology, Texas A&M Health Science Center, Houston, TX 77030, USA.
Our group has synthesized a pleiotropic synthetic nanozyme redox mediator we term a "pleozyme" that displays multiple enzymatic characteristics, including acting as a superoxide dismutase mimetic, oxidizing NADH to NAD, and oxidizing HS to polysulfides and thiosulfate. Benefits have been seen in acute and chronic neurological disease models. The molecule is sourced from coconut-derived activated charcoal that has undergone harsh oxidization with fuming nitric acid, which alters the structure and chemical characteristics, yielding 3-8 nm discs with broad redox potential.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
Center for Genomics and Precision Medicine, Institute of Bioscience and Technology, Texas A&M Health Science Center, Houston, TX 77030, USA.
Harsh acid oxidation of activated charcoal transforms an insoluble carbon-rich source into water-soluble, disc structures of graphene decorated with multiple oxygen-containing functionalities. We term these pleiotropic nano-enzymes as "pleozymes". A broad redox potential spans many crucial redox reactions including the oxidation of hydrogen sulfide (HS) to polysulfides and thiosulfate, dismutation of the superoxide radical (O*), and oxidation of NADH to NAD.
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