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Boronated enynes as versatile sources of stereodefined and skeletally diverse molecules. | LitMetric
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Boronated enynes as versatile sources of stereodefined and skeletally diverse molecules.

Alain Hercouet Fabienne Berrée Chia Hui Lin Loïc Toupet Bertrand Carboni

Org Lett

Ingéniérie Chimique et Molécules pour le Vivant, Sciences Chimiques de Rennes, UMR 6226, Rennes CEDEX, France.

Published: April 2007

[reaction: see text] The application of a one-pot palladium-catalyzed cycloisomerization of enynes 1/Diels-Alder cycloaddition/allylboration sequence efficiently generates tricyclic structures with complete control of the four stereogenic centers. Ruthenium and platinum catalysts perform distinct transformations providing other isomeric boron-substituted cyclic compounds.

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 Source
http://dx.doi.org/10.1021/ol070400sDOI Listing

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