A conjugated alternating copolymer containing norbornadiene and bis(ethynylene)phenylene units was prepared by the Cassar-Heck-Sonogashira cross-coupling reaction. Its electroluminescence was tested in a device, and its fluorescence colour could be tuned by light-induced norbornadiene-quadricyclane isomerization.

Download full-text PDF

Source
http://dx.doi.org/10.1039/b611685jDOI Listing

Publication Analysis

Top Keywords

photochemical tuning
4
tuning light
4
light emission
4
emission conjugated
4
conjugated polymer
4
polymer norbornadiene
4
norbornadiene units
4
units main
4
main chain
4
chain conjugated
4

Similar Publications

A covalent organic framework (COF) has emerged as a promising photocatalyst for the removal of pharmaceutical and personal care product (PPCP) contaminants; however, high-performance COF photocatalysts are still scarce. In this study, three COF photocatalysts were successfully synthesized by the condensation of benzo[1,2-b:3,4-b':5,6-b'']trithiophene-2,5,8-tricarbaldehyde (BTT) with 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trianiline (TAPT), 1,3,5-Tris(4-aminophenyl)benzene (TAPB), and 4,4',4''-nitrilotris(benzenamine) (TAPA), namely, BTT-TAPA, BTT-TAPB, and BTT-TAPT, respectively. The surface areas of BTT-TAPA, BTT-TAPB, and BTT-TAPT were found to be 800.

View Article and Find Full Text PDF

Enzymes are attractive as catalysts due to their specificity and biocompatibility; however, their use in industrial and biomedical applications is limited by stability. Here, we present a facile approach for enzyme immobilization within "all-enzyme" hydrogels by forming photochemical covalent cross-links between the enzyme glucose oxidase. We demonstrate that the mechanical properties of the enzyme hydrogel can be tuned with enzyme concentration and the data suggests that the dimeric nature of glucose oxidase results in unusual gel formation behavior which suggests a degree of forced induced dimer dissociation and unfolding.

View Article and Find Full Text PDF

This study focuses on enhancing the performance of photodetector through the utilization of inorganic perovskite material. It emphasizes that the unique properties of perovskite materials contribute to the superior performance of the photodetector. The focus is on the design and enhancement of CsSnI-based photodetector having graphene oxide (GO) and PCBM as charge transport layer, analysing their potential for improved operation.

View Article and Find Full Text PDF

Metal chalcogenide quantum dots for photochemical and electrochemical hydrogen generation: recent advancements and technological challenges.

Nanotechnology

January 2025

Nanochemistry Laboratory, Department of Chemistry, Jamia Millia Islamia, New Delhi 110025, India.

The performance of heterogeneous catalysis, specifically photochemical and electrochemical hydrogen evolution reaction (HER) fundamentally relies upon the prudent choice of catalytic systems with ideal optoelectronic and surface properties. Progressive research in materials processing has hinted at the large-scale applicability of two-dimensional (2D) materials for achieving higher activity in the HER process. Among 2D materials, transition metal chalcogenides (TMCs) have emerged as the advanced materials to enhance the rate of HER on account of their layered structure and chalcogen-sites that exhibit favorable hydrogen binding energies.

View Article and Find Full Text PDF

In an effort to meet the high demand for silver nanostructures in both research and consumer applications, we devise a simple and readily scaleable photochemical method through which silver nanostructures of varying morphologies, sizes, and optical properties can be synthesized using batch and flow photochemical strategies. For the latter we build upon the application of a wrapped-lamp photochemical flow system recently developed by our group to enable sequential irradiation with several wavelengths of LEDs in series in an approach that we describe as "plasmon pushing". We find that this strategy can accelerate the conversion of silver nanoparticle seeds to decahedral and triangular nanostructures, and that with it we have control over the tuning of the size and optical properties of triangular nanostructures in the red and near-IR regions.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!