A conjugated alternating copolymer containing norbornadiene and bis(ethynylene)phenylene units was prepared by the Cassar-Heck-Sonogashira cross-coupling reaction. Its electroluminescence was tested in a device, and its fluorescence colour could be tuned by light-induced norbornadiene-quadricyclane isomerization.
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Molecules
January 2025
Yunnan Key Laboratory of Metal-Organic Molecular Materials and Device, Kunming University, Kunming 650214, China.
A covalent organic framework (COF) has emerged as a promising photocatalyst for the removal of pharmaceutical and personal care product (PPCP) contaminants; however, high-performance COF photocatalysts are still scarce. In this study, three COF photocatalysts were successfully synthesized by the condensation of benzo[1,2-b:3,4-b':5,6-b'']trithiophene-2,5,8-tricarbaldehyde (BTT) with 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trianiline (TAPT), 1,3,5-Tris(4-aminophenyl)benzene (TAPB), and 4,4',4''-nitrilotris(benzenamine) (TAPA), namely, BTT-TAPA, BTT-TAPB, and BTT-TAPT, respectively. The surface areas of BTT-TAPA, BTT-TAPB, and BTT-TAPT were found to be 800.
View Article and Find Full Text PDFBiomacromolecules
January 2025
School of Physics and Astronomy, University of Leeds, Leeds LS2 9JT, U.K.
Enzymes are attractive as catalysts due to their specificity and biocompatibility; however, their use in industrial and biomedical applications is limited by stability. Here, we present a facile approach for enzyme immobilization within "all-enzyme" hydrogels by forming photochemical covalent cross-links between the enzyme glucose oxidase. We demonstrate that the mechanical properties of the enzyme hydrogel can be tuned with enzyme concentration and the data suggests that the dimeric nature of glucose oxidase results in unusual gel formation behavior which suggests a degree of forced induced dimer dissociation and unfolding.
View Article and Find Full Text PDFLuminescence
January 2025
Department of Electronics and Communication Engineering, Madan Mohan Malaviya University of Technology, Gorakhpur, Uttar Pradesh, India.
This study focuses on enhancing the performance of photodetector through the utilization of inorganic perovskite material. It emphasizes that the unique properties of perovskite materials contribute to the superior performance of the photodetector. The focus is on the design and enhancement of CsSnI-based photodetector having graphene oxide (GO) and PCBM as charge transport layer, analysing their potential for improved operation.
View Article and Find Full Text PDFNanotechnology
January 2025
Nanochemistry Laboratory, Department of Chemistry, Jamia Millia Islamia, New Delhi 110025, India.
The performance of heterogeneous catalysis, specifically photochemical and electrochemical hydrogen evolution reaction (HER) fundamentally relies upon the prudent choice of catalytic systems with ideal optoelectronic and surface properties. Progressive research in materials processing has hinted at the large-scale applicability of two-dimensional (2D) materials for achieving higher activity in the HER process. Among 2D materials, transition metal chalcogenides (TMCs) have emerged as the advanced materials to enhance the rate of HER on account of their layered structure and chalcogen-sites that exhibit favorable hydrogen binding energies.
View Article and Find Full Text PDFNanoscale Adv
December 2024
Department of Chemistry and Biomolecular Sciences, University of Ottawa Ottawa Ontario K1N 6N5 Canada
In an effort to meet the high demand for silver nanostructures in both research and consumer applications, we devise a simple and readily scaleable photochemical method through which silver nanostructures of varying morphologies, sizes, and optical properties can be synthesized using batch and flow photochemical strategies. For the latter we build upon the application of a wrapped-lamp photochemical flow system recently developed by our group to enable sequential irradiation with several wavelengths of LEDs in series in an approach that we describe as "plasmon pushing". We find that this strategy can accelerate the conversion of silver nanoparticle seeds to decahedral and triangular nanostructures, and that with it we have control over the tuning of the size and optical properties of triangular nanostructures in the red and near-IR regions.
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