The effect of hydrostatic pressure on chemical reactions induced by 20 kHz ultrasound has been studied using three different methods: the oxidation of potassium iodide, bubble cloud visualization studies, and sound attenuation measurements. The latter two have demonstrated that shielding of the ultrasonic wave is less pronounced at elevated pressures. Accordingly, the yield of iodine liberation increases with increasing pressure. At high static pressures, however, the less efficient cavitation dynamics dominate and the chemical reactivity decreases rapidly.
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http://dx.doi.org/10.1021/jp070635l | DOI Listing |
Spectrochim Acta A Mol Biomol Spectrosc
March 2025
Faculty of Science, Hokkaido University, N10 W8, Kita-ku, Sapporo, Hokkaido 060-0810, Japan.
The phase changes and reactivity of 1-pentadecene (CH) were investigated using Raman spectroscopy under high-pressure and high-temperature conditions using diamond anvil cells. At room temperature, the phase changes from liquid phase to solid phase I, and solid phase I to solid phase II were observed at 0.3 GPa and 4.
View Article and Find Full Text PDFPLoS One
December 2024
Faculty of Medicine, University of Oslo, Oslo, Norway.
Recently intermittent negative pressure has emerged as a potential treatment in vascular disease and has similarities with established experimental interventions such as lower body negative pressure. The direct, local influences of either method upon intravascular pressure still require some clarification however, particularly in the immediate moments following onset. We investigated the acute intravascular pressure responses to intermittent cycles of negative pressure in the supine and sitting postures.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
October 2024
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
Two-dimensional (2D) <100>-oriented perovskites exhibit superior optoelectronic properties, offering significant potential in photovoltaic, light-emitting, and photodetection applications. Nevertheless, their enlarged interlayer spacing restricts longitudinal carrier transport, thereby limiting its potential applications. While <110>-oriented 2D perovskites provide a prospective solution with their compact interlayer spacing, their inherent structure, characterized by octahedra tilting, indirectly hinders carrier transport due to the generation of self-trapped excitons (STEs) caused by strong electron-phonon coupling.
View Article and Find Full Text PDFSensors (Basel)
September 2024
Petroleum Engineering Department, Texas A&M University, College Station, TX 77843, USA.
ACS Appl Mater Interfaces
October 2024
Key Laboratory of Functional Materials Physics and Chemistry (Ministry of Education), College of Physics, Jilin Normal University, Changchun 130103, China.
For the first time, an innovative pressure quenching technique is used to create the integrated electrode of the black phosphorus (BP) @TiCT composite material, doing away with the requirement for adhesive additives and simplifying time-consuming processes. Through the formation of Ti-O-P bonds with BP, TiCT MXenes can function as conductive additives and affect the interlayer gap. Additionally, we have found that there is a critical synthetic pressure threshold (300 kN) at which the performance of BP@TiCT-integrated electrodes can be improved: too high of a pressure prevents lithium-ion transport because of mesopore reduction; too low of a pressure prevents Ti-O-P chemical bond formation between the two components; and suboptimal pressure does not allow for density enhancement for better electron conduction.
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