AI Article Synopsis
- The review highlights recent developments in the chemistry of pnictogen(III)-nitrogen ring systems, specifically cyclopnict(III)azanes.
- It compares the synthetic methods and reactions of these heavier pnictogen systems to the established chemistry of cyclophosph(III)azanes.
- Key areas of focus include ring-oligomerization processes and utilizing four-membered E(2)N(2) rings for creating larger macrocyclic structures, alongside a discussion of main-group element and transition-metal complexes.
Article Abstract
This critical review covers significant recent advances in the chemistry of pnictogen(III)-nitrogen ring systems, also known as cyclopnict(III)azanes. The synthetic methodologies and reactions of the heavier pnictogen systems are compared with the well-developed chemistry of cyclophosph(III)azanes. Particular attention is focused on ring-oligomerization processes and the use of four-membered E(2)N(2) rings as building blocks for the synthesis of macrocyclic molecules. Main-group element and transition-metal complexes are also discussed (95 references).
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| http://dx.doi.org/10.1039/b514861h | DOI Listing |
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