Synthesis and structural characterization of BaV4O9.

Acta Crystallogr B

Institut für Kristallographie der RWTH Aachen, Jägerstrasse 17-19, 52066 Aachen, Germany.

Published: April 2007

The new spin (1/2) V(4+) barium oxovanadate BaV(4)O(9) was synthesized and studied by means of single-crystal X-ray diffraction. Its room-temperature structure is monoclinic, space group P2/c. We discuss the temperature evolution of the crystal structure and thermal expansion tensor of the material between 293 and 100 K.

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http://dx.doi.org/10.1107/S0108768107003734DOI Listing

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