The binuclear complex of Schiff base C14H12NO3K(KHL) derived from 2-hydroxy-l-naphthaldehyde and beta-alanine with lanthanide nitrate was synthesized and characterized by elemental analysis, IR, UV, TG-DTA, and molar conductance analysis. The composition of the complex was [La2(L)2 (NO3)2] x 2C2H5OH. The interaction of the complex and DNA was studied by fluorescence spectrum. The result indicates that the La(III) complex could cause a sharp decrease in the fluorescence intensity of EB-DNA system, and the complex could partly sustain the place of EB.
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Inorg Chem
January 2025
Grupo NanoToxGen, Centro Interdisciplinar de Química y Biología (CICA), Departamento de Química, Facultade de Ciencias, Universidade da Coruña, A Coruna 15071, Spain.
Symmetrical bis(hydrazone)-based ligands, Hdar(bhz) (), Hdar(fah) (), Hdar(nah) (), and Hdar(inh) () obtained from 4,6-diacetylresorcinol (Hdar) and different hydrazides [benzoylhydrazide (Hbhz), isonicotinoylhydrazide (Hinh), nicotinoylhydrazide (Hnah), and 2-furoylhydrazide (Hfah)], were used to prepare potassium salts of binuclear -[VO] complexes, {K(HO)}[(VO)dar(bhz)] (), {K(HO)}[(VO)dar(fah)] (), {K(HO)}[(VO)dar(nah)] (), and {K(HO)}[(VO)dar(inh)] (), and binuclear [VO] complexes, [{VO(MeOH)}dar(bhz)] (), [{VO(MeOH)}dar(fah)] (), [{VO(MeOH)}dar(nah)] (), and [{VO(MeOH)}dar(inh)] (). In the presence of warm MeOH/DMSO (4:1), changed to {K(HO)}[(VO)Hdar(nah)]DMSO (·DMSO). Single crystal XRD studies of and confirm a binuclear structure along with a distorted square pyramidal geometry of each vanadium center where bis{ONO(2-)} ligands coordinate through phenolate-O, azomethine-N, and enolate-O atoms of each unit.
View Article and Find Full Text PDFBiophys J
January 2025
Department of Physics, Northeastern University, Boston, MA, 02115, USA. Electronic address:
Binuclear ruthenium complexes have been investigated for potential DNA-targeted therapeutic and diagnostic applications. Studies of DNA threading intercalation, in which DNA base pairs must be broken for intercalation, have revealed means of optimizing a model binuclear ruthenium complex to obtain reversible DNA-ligand assemblies with the desired properties of high affinity and slow kinetics. Here, we used single-molecule force spectroscopy to study a binuclear ruthenium complex with a longer semi-rigid linker relative to the model complex.
View Article and Find Full Text PDFInorg Chem
January 2025
Department of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, 3012 Bern, Switzerland.
Binuclear silver(I) and copper(I) complexes, and , with bridging diphenylphosphine ligands were prepared. In , the silver(I) center is located inside a trigonal plane composed of three phosphorus donors from three separate and bridging dppm ligands. The fourth coordination site is filled with neighboring silver(I) ions.
View Article and Find Full Text PDFDalton Trans
January 2025
Department of Chemistry, Indian Institute of Technology Kharagpur, Kharagpur, 721302 India.
The reaction between 1,3-bis(3,5-dimethylpyrazolylmethyl)hexahydropyrimidine L and Mo(CO) in CHCN at 130 °C afforded a binuclear Mo(0) complex 1 containing a new macrocycle formed upon C-N bond cleavage in L in good yield. Conversely, a clean reaction takes place between L and [Mo(CO)(COD)] in THF at 60 °C to give a new metalloligand complex [Mo(CO)(κ-,-L)] 2 containing a spectator pyrazole arm in 83% yield. Their structures were determined by X-ray diffraction methods, and a plausible mechanism is proposed for the C-N bond cleavage leading to complex 1.
View Article and Find Full Text PDFTurk J Chem
October 2024
Supramolecular Compounds Division, Institute of General and Inorganic Chemistry, Uzbekistan Academy of Sciences, Tashkent, Uzbekistan.
The cocrystal (or supramolecular complex) between the Cu(II) complex of salicylic acid and uncoordinated piracetam has been synthesized. Its structure is characterized by elemental analysis, FT-IR, UV-Vis spectroscopy, and X-ray crystallography. Spectroscopic methods confirm the formation of the metal complex, while X-ray crystallography establishes the molecular and crystal structure of the obtained compound.
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