We compute the leading-order low-energy constants of the DeltaS=1 effective weak Hamiltonian in the quenched approximation of QCD with up, down, strange, and charm quarks degenerate and light. They are extracted by comparing the predictions of finite-volume chiral perturbation theory with lattice QCD computations of suitable correlation functions carried out with quark masses ranging from a few MeV up to half of the physical strange mass. We observe a DeltaI=1/2 enhancement in this corner of the parameter space of the theory. Although matching with the experimental result is not observed for the DeltaI=1/2 amplitude, our computation suggests large QCD contributions to the physical DeltaI=1/2 rule in the GIM limit, and represents the first step to quantify the role of the charm-quark mass in K-->pipi amplitudes. The use of fermions with an exact chiral symmetry is an essential ingredient in our computation.
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Dalton Trans
November 2022
Universität zu Köln, Department für Chemie, Institut für Anorganische Chemie, Greinstraße 6, D-50939 Köln, Germany.
A series of cyclometalated Pt(II) complexes [Pt(C^N^N)X] (X = Cl, CCPh, CCCF) was synthesised from the protoligands HC^N^N containing either phenyl (ph), naphthyl (na) or (benzo)thiophenyl (b(th)) functions and either pyridyl (py) or (benzo)thiazolyl ((b)tz) units, alongside the central 4-phenyl-pyridyl (ppy) or Bu-phenyl-pyridyl (tbppy) group. Depending on the combination of the or building blocks, these square planar complexes reveal very different electrochemical, UV-vis absorption and emission behaviour. The reversible reductions shift anodically along the series th/py < ph/tz ≈ th/tz < ph/btz while the irreversible oxidations shift cathodically along the series Cl ≈ CCCF < CCPh.
View Article and Find Full Text PDFEur Phys J C Part Fields
May 2022
Physik-Institut, Universität Zürich, Winterthurerstrasse 190, 8057 Zürich, Switzerland.
The electromagnetic form factors of charged and neutral kaons are strongly constrained by their low-energy singularities, in the isovector part from two-pion intermediate states and in the isoscalar contribution in terms of and residues. The former can be predicted using the respective partial-wave amplitude and the pion electromagnetic form factor, while the latter parameters need to be determined from electromagnetic reactions involving kaons. We present a global analysis of time- and spacelike data that implements all of these constraints.
View Article and Find Full Text PDFJ Phys Chem A
February 2021
Department of Chemistry, Fu-Jen Catholic University, New Taipei City 24205, Taiwan, ROC.
Efficient charge-transfer (CT) phosphorescence in the near-IR (NIR) spectral region is reported for four substituted Ru-(R-dipyrrinato) complexes, [Ru(bpy)(R-dipy)](PF), where bpy is 2,2'-bipyridine and the substituent R is phenyl (ph), 2,4,6-trimethylphenyl, 4-carboxyphenyl (HOOC-ph), or 4-pyridinyl. The experimentally determined phosphorescence efficiency, ι = /(ν) (where and ν are the phosphorescence rate constant and the phosphorescence frequency, respectively), of the [Ru(bpy)(R-dipy)] complexes was approximately double that of [Ru(bpy)(Am)] complexes (Am = ammine ligand) in the NIR region. Density functional theory (DFT) modeling indicated two strikingly different electronic configurations of the triplet emitting state (T) in the two types of complexes.
View Article and Find Full Text PDFMolecules
January 2020
Department of Chemistry, Case Western Reserve University, 10900 Euclid Ave., Cleveland, OH 44106, USA.
Sulfur-substituted DNA and RNA nucleobase derivatives (a.k.a.
View Article and Find Full Text PDFEur Phys J C Part Fields
July 2019
1Institute of Physics, École Polytechnique Fédérale de Lausanne (EPFL), Lausanne, Switzerland.
A method is proposed to measure the photon polarisation parameter in transitions using an amplitude analysis of decays. Simplified models of the system are used to simulate and decays, validate the amplitude analysis method, and demonstrate the feasibility of a measurement of the parameter irrespective of the model parameters. Similar sensitivities to are obtained with both the charged and neutral hadronic systems.
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